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References from Cation‐Regulated [CH 3 BO 2 F]‐Derived Borates: Synergistic Fluorination and Organic Functionalization for High‐Birefringence UV NLO Materials. Local targets link to admitted publications; unresolved targets remain external evidence.
Borates: A Rich Source for Optical Materials
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Recent Advances in Ultraviolet and Deep‐Ultraviolet Second‐Order Nonlinear Optical Crystals
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The Role of Cations in Second‐Order Nonlinear Optical Materials Based on π‐Conjugated [BO3]3− Groups
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First‐Principles Design and Simulations Promote the Development of Nonlinear Optical Crystals
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Recent Advances in Rational Structure Design for Nonlinear Optical Crystals: Leveraging Advantageous Templates
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Two Metal Phosphate Nonlinear Optical Materials Simultaneously Exhibiting Ultraviolet Transparence and a Large Birefringence
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Recent Progress in Structural Design Strategies of High‐Birefringence Optical Crystals
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Fluorooxoborates: A Precious Treasure of Deep‐Ultraviolet Nonlinear Optical Materials
10.1016/j.cjsc.2023.100027 · 2023 · External reference
Synthesis and Characterization of the Tin Iodide Borate Sn3[B3O7]I
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Rational Design via Synergistic Combination Leads to an Outstanding Deep‐Ultraviolet Birefringent Li2Na2B2O5 Material with an Unvalued B2O5 Functional Gene
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Assembly of π‐Conjugated [B3O6] Units by Mer‐Isomer [YO3F3] Octahedra to Design a UV Nonlinear Optical Material
10.1002/anie.202406318 · 2024 · External reference
An Unprecedented [BO2]‐Based Deep‐Ultraviolet Transparent Nonlinear Optical Crystal by Superhalogen Substitution
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Superhalogens Beget Superhalogens: A Case Study of (BO2) n Oligomers
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Be2(BO3)(IO3): The First Anion‐Mixed Van der Waals Member in the KBe2BO3F2 Family with a Very Strong Second Harmonic Generation Response
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A Promising Deep Ultraviolet Nonlinear Optical Crystal Activated by the Ordered Structure Design
2025 · External reference
Aluminoborates as Nonlinear Optical Materials
10.1002/anie.202217037 · 2023 · External reference
Na[B3IO7(OH)] and Na2[B4IO9](IO3): Explorations of Boroiodates with Strong Second Harmonic Generation Response and Large Birefringence
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Stable Oxoborate with Edge‐Sharing BO4 Tetrahedra Synthesized under Ambient Pressure
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Tetrahedra in a Borosulfate: Synthesis, Crystal Structure, and Quantum‐Chemical Investigation of Sr
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Cs3[(BOP)2(B3O7)3]: A Deep‐Ultraviolet Nonlinear Optical Crystal Designed by Optimizing Matching of Cation and Anion Groups
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Assembly of π‐Conjugated [B3O7] Groups by Unprecedented Antiparallel Triangles [ZnO3] to Tailor a Deep‐UV Zinc Borate Birefringent Crystal
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A Bifunctional Primitive Strategy Induces Enhancements of Large Second Harmonic Generation and Wide UV Transmittance in Rare‐Earth Borates Containing [B5O10] Groups
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New Nonlinear‐Optical Crystal: LiB3O5
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Linear and Nonlinear Optical Properties of the KBe2BO3F2 (KBBF) Crystal
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Breaking Through the “200 nm Deep‐Ultraviolet Wall” of Phase Matching Region by Cation Structural Modulation
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Flux Crystal Growth of the Extended Structure Pu(V) Borate Na2(PuO2)(BO3)
10.1021/jacs.2c11355 · 2023 · External reference
Recent Progress in Ultraviolet and Deep‐Ultraviolet Nonlinear Optical Aluminoborates
10.1016/j.cjsc.2023.100036 · 2023 · External reference
Review of KBe2BO3F2‐Like Second‐Order Nonlinear Optical Materials and Their Structure‐Performance Relationships
10.1016/j.ccr.2025.216632 · 2025 · External reference
KMB4O6F3 (M = Co, Fe): Two‐Dimensional Magnetic Fluorooxoborates with Triangular Lattices Directed by Triangular BO3 Units
10.1039/d3dt02394j · 2023 · External reference
Constructing Deep‐Ultraviolet Nonlinear Optical Crystals via Synergistic Combination of Fluorinated Polyhedra and Polymerized BO3 Units
10.1002/adfm.202531049 · 2026 · External reference
Vacuum Ultraviolet Second‐harmonic Generation in NH4B4O6F Crystal
10.1038/s41586-025-10007-z · 2026 · External reference
Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials
10.1002/anie.201712168 · 2018 · External reference
CsB4O6F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units
10.1002/anie.201708231 · 2017 · External reference
SrB5O7F3 Functionalized with [B5O9F3]6− Chromophores: Accelerating the Rational Design of Deep‐Ultraviolet Nonlinear Optical Materials
10.1002/anie.201802058 · 2018 · External reference
NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5O m (OH) n ] Units and Deep Ultraviolet Cutoff Edges
10.1021/acs.inorgchem.4c01030 · 2024 · External reference
Realizing Deep‐Ultraviolet Second Harmonic Generation by First‐Principles‐Guided Materials Exploration in Hydroxyborates
10.1021/jacs.0c07256 · 2020 · External reference
Two Melamine Borates with Large Birefringence
10.1021/acs.inorgchem.4c04170 · 2024 · External reference
Perfluoroalkyl Borates: Congeners of Perfluoroalkanes
10.1016/s0010-8545(01)00318-6 · 2021 · External reference
Pentaborate Polyanion in the Crystal Structure of Ulexite, NaCaB5O6(OH)6·5H2O
10.1126/science.145.3638.1295 · 1964 · External reference
Strong SHG Responses in a Beryllium‐Free Deep‐UV‐Transparent Hydroxyborate via Covalent Bond Modification
10.1002/anie.202113397 · 2021 · External reference
A New Acentric Borate of Ba2[B5O8(OH)]2[B(OH)3]·H2O: Synthesis, Structure and Nonlinear Optical Property
10.1016/j.inoche.2020.108220 · 2020 · External reference
Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species
10.1002/anie.202205060 · 2022 · External reference
Asymmetry‐Driven Organic–Inorganic Hybrid Strategy for Constructing Structures with Exceptional Organofunctionalized B–O Units
10.1039/d5qi02384j · 2026 · External reference
Structure‐Property Relationship in Nonlinear Optical Materials with π‐conjugated CO3 Triangles
10.1016/j.ccr.2019.213152 · 2020 · External reference
Breaking the Birefringence Barrier in B–O Crystals via B–C π‐scaffolding
10.1021/jacs.5c06328 · 2025 · External reference
NaZnCO3(OH): A High‐Performance Carbonate Ultraviolet Nonlinear Optical Crystal Derived from KBe2BO3F2
10.1021/jacs.0c09866 · 2020 · External reference
Low Temperature Molten Salt Synthesis of Noncentrosymmetric (NH4)3SbF3(NO3)3 and Centrosymmetric (NH4)3SbF4(NO3)2
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Second‐Order Nonlinear Optical Crystals with Mixed Anions
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Quadruple‐Bidentate Nitrate‐Ligated A2Hg(NO3)4(A=K, Rb): Strong Second‐Harmonic Generation and Sufficient Birefringence
2023 · External reference
Ln(HCOO)3 (Ln = Y, Gd, Ce, and La) with Triangular Configuration Exhibits Excellent UV Nonlinear Optical Performance
10.1002/smll.202412404 · 2025 · External reference
Rational Design of the Metal‐Free KBe2BO3F2·(KBBF) Family Member C(NH2)3SO3F with Ultraviolet Optical Nonlinearity
10.1002/anie.202006671 · 2020 · External reference
Design of the Ionic Organic Nonlinear Optical Material NH4[LiC3H(CH3)O4] with Ultrawide Band Gap and Moderate Birefringence
10.1002/anie.202304858 · 2023 · External reference
A High‐Performance Nonlinear Optical Crystal with a Building Block Containing Expanded π‐Delocalization
2023 · External reference
Unprecedented Deep Ultraviolet (DUV) Birefringence in Fluorides Constructed from Linear π‐Group Anisotropic Structure Building Units
2025 · External reference
New Functional Groups Design toward High Performance Ultraviolet Nonlinear Optical Materials
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UV Solar‐Blind‐Region Phase‐Matchable Optical Nonlinearity and Anisotropy in a π‐Conjugated Cation‐Containing Phosphate
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Polymorphic Pb14O8I12 and Pb7O4I6 Oxyhalides Featuring Unprecedented [O8Pb14] Clusters with Broad IR Transparency
10.1007/s40843-021-1799-3 · 2020 · External reference
Advances in Aliovalent Substitution Strategy for the Design and Synthesis of Nonlinear Optical Materials: D0 Transition Metal/Gallium Iodates and Selenites
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Covalent Interlayer Engineering Enables Ideal Birefringence and Strong SHG in Beryllium‐Free Deep‐UV NLO Borates
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Bi3of3(IO3)4: Metal Oxyiodate Fluoride Featuring a Carbon‐Nanotube‐like Topological Structure with Large Second Harmonic Generation Response
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Achieving the Full‐Wavelength Phase‐Matching for Efficient Nonlinear Optical Frequency Conversion in C(NH2)3BF4
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