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References from Synthetic strategies and applications of positional thiol analogs of glycopyranose. Local targets link to admitted publications; unresolved targets remain external evidence.
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Design, synthesis, and biological evaluation of thioglucoside analogues of gliflozin as potent new gliflozin drugs
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Aromatic thioglycoside inhibitors against the virulence factor LecA from Pseudomonas aeruginosa
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Synthesis of oligosaccharides containing the S-galp (α1→3) galp unit, glycomimetic of the epitope recognized by lytic antibodies
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10.1016/j.tet.2015.04.060 · 2015 · External reference
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Recent advances in transition-metal-catalyzed functionalization of 1-thiosugars
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Copper-mediated radical transformation of protection-free Glycosylsulfonohydrazide for access to diverse glycosides
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Palladium-catalyzed stereospecific S-glycosylation by allylic substitution
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Regio- and stereo-selective synthesis of 1β−/3R-aryl Thiosugar
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Recent advances in the synthesis of thiosugars using glycal donors
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Stereoselective synthesis of β-S-glycosides via palladium catalysis
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β-Thioglycosylation from Unactivated carbohydrates
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Catalyst-controlled Regiodivergent synthesis of 1-and 3-Thiosugars with high Stereoselectivity and Chemoselectivity
10.1021/acscatal.1c00225 · 2021 · External reference
How do multivalent glycodendrimers benefit from sulfur chemistry
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New syntheses of thiosaccharides utilizing substitution reactions
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Thioglycosides in carbohydrate research
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Recent advances in direct synthesis of 2-deoxy glycosides and thioglycosides
10.1016/j.tet.2021.132140 · 2021 · External reference
Exploring the chemistry and applications of thio-, seleno-, and tellurosugars
10.3390/molecules30092053 · 2025 · External reference
Transition-metal-mediated glycosylation with thioglycosides
2022 · External reference
Derivatives of d-thioxylopyranose and of some reducing 1-deoxy-1-thiodisaccharides
10.1135/cccc19650297 · 1965 · External reference
Carbohydrate-derived thiols as protic polarity-reversal catalysts for enantioselective radical-chain reactions
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Improved synthesis of glucosinolates
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Reaction of 1,2-trans-glycosyl acetates with thiourea: a new entry to 1-thiosugars
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Novel synthesis of 1-thioglycopyranoses via thioiminium salts
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Efficient stereoselective synthesis of 1-thio-β-mannopyranosides
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Sialoside clusters as potential ligands for siglecs (sialoadhesins)
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Design, chemical synthesis, and biological evaluation of thiosaccharide analogues of morphine- and codeine-6-glucuronide
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Mild, selective deprotection of thioacetates using sodium thiomethoxide
10.1016/s0040-4039(98)00421-3 · 1998 · External reference
Selective S-deacetylation inspired by native chemical ligation: practical syntheses of glycosyl thiols and drug mercapto-analogues
10.1039/c5gc00084j · 2015 · External reference
Selective S-deacetylation of functionalized Thioacetates catalyzed by Dy (OTf)3
10.1002/ajoc.201700481 · 2018 · External reference
Straightforward S–S bond formation via the oxidation of S-acetyl by iodine in the presence of N-iodosuccinimide
10.1021/acs.joc.7b02367 · 2017 · External reference
The oxidation of S-acetyl by nitrite: mechanism and application
10.1002/slct.202003566 · 2020 · External reference
Improved synthesis of 1-glycosyl thioacetates and its application in the synthesis of thioglucoside gliflozin analogues
10.1002/ejoc.202100357 · 2021 · External reference
Stereoselective synthesis of 1,2-cis-α-glycosyl thiols and trehalose-type α, α’-thiodisaccharides by cryo thiol-ene photocoupling-thio-click reaction in frozen state
10.1002/chem.202500104 · 2025 · External reference
The direct formation of glycosyl thiols from reducing sugars allows one-pot protein glycoconjugation
10.1002/anie.200600685 · 2006 · External reference
Synthesis of α-glycosyl thiols by stereospecific ring-opening of 1,6-anhydrosugars
10.1021/jo202069y · 2011 · External reference
A direct and stereospecific approach to the synthesis of α-glycosyl thiols
10.1039/b804536d · 2008 · External reference
Synthesis of glycosylthiols and reactivity studies
10.1021/jo200624e · 2011 · External reference
Efficient generation of thiolate sugars from glycosyl Bunte salts and its application to S-glycoside synthesis
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Stereoselective synthesis of β-glycosyl thiols and their synthetic applications
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Appel-reagent-mediated transformation of glycosyl hemiacetal derivatives into thioglycosides and glycosyl thiols
10.3762/bjoc.9.112 · 2013 · External reference
Straightforward stereoselective synthesis of 1-thio-β-d-mannosides and 1-thio-β-l-rhamnosides
10.1016/j.tetlet.2023.154391 · 2023 · External reference
Expeditious preparation of 1,6-anhydro-1-thio-β-d-hexopyranose derivatives
10.1016/j.carres.2023.108765 · 2023 · External reference
One-pot synthesis of unprotected anomeric glycosyl thiols in water for glycan ligation reactions with highly functionalized sugars
10.1002/anie.201607228 · 2016 · External reference
pH-dependent mutarotation of 1-thioaldoses in water. Unexpected behavior of (2S)-d-aldopyranoses
10.1021/jo100826e · 2010 · External reference
Stereoselective epimerizations of glycosyl thiols
10.1021/acs.orglett.7b02760 · 2017 · External reference
Synthesis of α-S-glycosphingolipids based on uronic acids
10.1021/ol202042h · 2011 · External reference
NiCl2/Hdipm-catalyzed 2-OH-selective alkylation of glycoside trans-diols
10.1021/acs.orglett.5c04886 · 2025 · External reference
Site-switchable alkylation of carbohydrates controlled by inexpensive metal ion catalysts
10.1021/acscatal.5c01306 · 2025 · External reference
SnCl4 promoted efficient cleavage of acetal/ketal groups with the assistance of water in CH2Cl2
10.3390/molecules27238258 · 2022 · External reference
Efficient synthesis of 2-OH thioglycosides from glycals based on the reduction of aryl disulfides by NaBH4
10.3390/molecules27185980 · 2022 · External reference
SnCl2-catalyzed acetalation/selective benzoylation sequence for the synthesis of orthogonally protected glycosyl acceptors
10.1002/ejoc.202101565 · 2022 · External reference
Stannous chloride as a low toxicity and extremely cheap catalyst for regio−/site-selective acylation with unusually broad substrate scope
10.1039/d0gc02739a · 2020 · External reference
Regio/site-selective alkylation of substrates containing a cis-, 1,2- or 1,3-diol with ferric chloride and dipivaloylmethane as the catalytic system
10.1039/c9gc04126e · 2020 · External reference
Regioselective sulfonylation/acylation of carbohydrates catalyzed by FeCl3 combined with benzoyltrifluoroacetone and its mechanism study
10.1021/acs.joc.9b03128 · 2020 · External reference
Synthesis of positional thiol analogs of β-d-galactopyranose
10.1002/ejoc.200700364 · 2007 · External reference
Synthesis of deoxyglycosides by desulfurization under UV light
10.1021/acs.joc.7b00896 · 2017 · External reference
Streamlined iterative assembly of thio-oligosaccharides by aqueous S-glycosylation of diverse deoxythio sugars
10.1002/cssc.202102483 · 2022 · External reference
A one-pot method for removal of thioacetyl group via desulfurization under ultraviolet light to synthesize deoxyglycosides
10.1021/acs.orglett.9b02033 · 2019 · External reference
Improved synthesis of sulfur-sontaining glycosides by suppressing thioacetyl migration
10.3389/fchem.2020.00319 · 2020 · External reference
Efficient preparation of 2-SAc-glycosyl donors and investigation of their application in synthesis of 2-deoxyglycosides
10.1002/ejoc.202200533 · 2022 · External reference
Visible-light-promoted desulfurization to synthesize deoxyglycosides
10.1021/acs.joc.3c00046 · 2023 · External reference
Synthesis of 2-deoxyglycosides with exclusive β-configuration using 2-SAc glycosyl bromide donors
10.3390/molecules30010185 · 2025 · External reference
Synthesis of 2-thiocarbohydrates and their binding to Concanavalin A
10.1021/acs.joc.6b00987 · 2016 · External reference
Synthesis and immunochemical characterization of S-linked glycoconjugate vaccines against Candida albicans
10.1002/chem.200800352 · 2008 · External reference
Stereospecific Ester activation in nitrite-mediated carbohydrate epimerization
10.1021/jo052662i · 2006 · External reference
H-bonding activation in highly Regioselective acetylation of diols
10.1021/jo402036u · 2013 · External reference
Regioselective acetylation of diols and polyols by acetate catalysis: mechanism and application
10.1021/jo501343x · 2014 · External reference
Efficient synthesis of β-d-mannosides and β-d-talosides by double parallel or double serial inversion
10.1021/jo062643o · 2007 · External reference
Catalytic site-selective acylation of carbohydrates directed by cation–n interaction
10.1021/jacs.7b01412 · 2017 · External reference
Regio and stereoselective one-pot synthesis of 2-deoxy-3-thio pyranoses and their O-glycosides from glycals
10.1021/acs.joc.3c00146 · 2023 · External reference
Solvent-dependent, kinetically controlled stereoselective synthesis of 3-and 4-thioglycosides
10.1021/jo050650r · 2005 · External reference
Highly stereoselective synthesis of primary, secondary, and tertiary α-S-sialosides under Lewis acidic conditions
10.1021/ol301779e · 2012 · External reference
S-acetyl migration in synthesis of sulfur-containing glycosides
10.1016/j.tet.2014.07.014 · 2014 · External reference
Site-selective introduction of thiols in unprotected glycosides
10.1039/d3ob00817g · 2023 · External reference
Site-selective dehydroxy-chlorination of secondary alcohols in unprotected glycosides
10.1021/acs.orglett.2c01992 · 2022 · External reference
Direct stereoselective synthesis of β-thiomannosides
10.1021/jo9914667 · 2000 · External reference
Zemplén transesterification: a name reaction that has misled us for 90 years
10.1039/c4gc02006e · 2015 · External reference
10.1039/c8gc00814k
10.1039/c8gc00814k · External reference
Synthesis of 4-thio-d-glucopyranose and interconversion to 4-thio-d-glucofuranose
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Site-selective functionalization of hydroxyl groups in carbohydrate derivatives
10.1021/acs.chemrev.8b00442 · 2018 · External reference
Protecting-group-free S-glycosylation towards thioglycosides and thioglycopeptides in water
10.1039/d1gc00098e · 2021 · External reference
Quartz crystal microbalance bioaffinity sensor for rapid identification of glycosyldisulfide lectin inhibitors from a dynamic combinatorial library
10.1016/j.bios.2005.11.024 · 2006 · External reference
Acyl group migration in pyranosides as studied by experimental and computational methods
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Protecting group migrations in carbohydrate chemistry
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Supramolecular activation in triggered cascade inversion
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Reactions of some pyranoside diol monotriflates with nucleophiles and bases
10.1021/jo00052a058 · 1992 · External reference
Strategies for introducing sulfur atom in a sugar ring: synthesis of 5-thioaldopyranoses and their NMR data
10.1080/17415993.2019.1616734 · 2019 · External reference
Mild and practical synthesis of 5-thio-D-glucopyranose and its pentaacetate derivatives
2024 · External reference
The sulfur-linked analogue of O-GlcNAc (S-GlcNAc) is an enzymatically stable and reasonable structural surrogate for O-GlcNAc at the peptide and protein levels
10.1021/acs.biochem.7b00268 · 2017 · External reference
Synthesis of (1→3) thiodisaccharides of GlcNAc and the serendipitous formation of 2,3-dideoxy-(1→2)-thiodisaccharides through a vinyl azide intermediate
10.1021/acs.joc.9b01883 · 2020 · External reference
Synthesis of S-trifluoromethyl S-arylsulfoximine thioglycosides through Pd-catalyzed Migita cross-coupling
10.1002/ejoc.202000821 · 2020 · External reference
Bispecific thio-linked disaccharides as inhibitors of Pseudomonas aeruginosa lectins LecA (PA-IL) and LecB (PA-IIL): dual-targeting strategy
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Synthesis of thiomaltooligosaccharides by a thio-click approach
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Synthesis of S-linked Glycoconjugates and S-disaccharides by thiol-Ene coupling reaction of Enoses
10.1021/ol302098u · 2012 · External reference
Promotion of a reaction by cooling: stereoselective 1,2-cis-α-thioglycoconjugation by thiol-ene coupling at −80°C
10.1002/chem.201800668 · 2018 · External reference
Photoinitiated thiol-ene reactions of enoses: a powerful tool for stereoselective synthesis of glycomimetics with challenging glycosidic linkages
10.1002/chem.201905408 · 2020 · External reference
Synthesis of mannosidase-stable Man3 and Man4 glycans containing S-linked Manα1→ 2Man termini
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Expedient synthesis of an α-S-(1→ 6)-linked pentaglucosyl thiol
10.1039/c4ob01094a · 2014 · External reference
Facile formation of β-thioGlcNAc linkages to thiol-containing sugars, peptides, and proteins using a mutant GH20 hexosaminidase
10.1002/anie.201809928 · 2019 · External reference
Thioglycoligases: mutant glycosidases for thioglycoside synthesis
10.1002/ange.200390082 · 2003 · External reference
Expanding the thioglycoligase strategy to the synthesis of α-linked thioglycosides allows structural investigation of the parent enzyme/substrate complex
10.1021/ja057904a · 2006 · External reference
Thioglycosynthases: double mutant glycosidases that serve as scaffolds for thioglycoside synthesis
10.1039/b313155f · 2004 · External reference
Thiosugars: new perspectives regarding availability and potential biochemical and medicinal applications
10.1007/s00253-005-0156-x · 2005 · External reference
Visible-light-promoted direct desulfurization of glycosyl thiols to access C-glycosides
10.1038/s41467-024-53563-0 · 2024 · External reference
Photocatalytic synthesis of α-ketonyl glycosyl compounds from glycosyl thiols and silyl enol ethers
10.1021/acs.orglett.4c03124 · 2024 · External reference
Iridium photoredox-catalyzed stereoselective C-glycosylation with tetrafluoropyridin-4-yl thioglycosides: a facile synthesis of C-α/β-glucogallins and their antioxidant activity
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1-Thiosugars: from synthesis to applications
10.2174/0113852728314452240524112438 · 2025 · External reference
Mild and effective method for the nickel-catalyzed Arylation of Glycosyl thiols in aqueous surfactant solution
10.1021/acs.joc.4c02233 · 2024 · External reference
Access to Thioglycoconjugate bioorganometallic ferrocenes via a copper-catalyzed coupling
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Electrochemical Deoxygenative Thiolation of Preactivated alcohols and ketones
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Electrochemical nickel-catalyzed cross-coupling of glycosyl thiols with preactivated phenols and ketones
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Diaryliodonium salts: a journey from obscurity to fame
10.1002/anie.200904689 · 2009 · External reference
Synthesis of aryl thioglycosides by metal-free arylation of glycosyl thiols with diaryliodonium salts under basic conditions
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Site-selective S-Arylation of 1-Thiosugars with aryl Thianthrenium salts through copper(I)-mediated, Photoredox-catalyzed reactions
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Stereoretentive radical cross-coupling
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Visible-light-mediated synthesis of anomeric S-aryl glycosides via electron donor-acceptor complex using thianthrenium salts
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Electro-chemically dehydrogenative C(sp2)–H/S–H cross-coupling: efficient synthesis of ortho-aminophenyl thioglycoside derivatives
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Iodine-catalyzed thioglycosylation of indole and tryptophan-containing peptides with thioglycosides
10.1021/acs.joc.5c01715 · 2025 · External reference
Stereoretentive palladium-catalyzed arylation, alkenylation, and alkynylation of 1-thiosugars and thiols using aminobiphenyl palladacycle precatalyst at room temperature
10.1002/chem.201501050 · 2015 · External reference
Synthesis of (1→2)-S-linked saccharides and S-linked glycoconjugates via a palladium-G3-xantphos pre-catalyst catalysis
10.1021/acs.joc.7b00861 · 2017 · External reference
Pd-catalyzed synthesis of 1-(hetero)aryl Thioglycosides: strategy for the trapping of an acyl Group of Glycosylthioesters by coupling of Bis-electrophilic−nucleophilic partners
10.1021/acs.joc.4c01867 · 2024 · External reference
Pd-catalyzed direct S−C cross-coupling with Glycosyl 1-Thioacetates to synthesize Thioglucoside analogues of Gliflozins
2026 · External reference
Photoinitiated thiol-ene mediated functionalisation of 4, 5-enoses
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Applications of thiol-ene chemistry for peptide science
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Photoinduced thiol-ene coupling as a click ligation tool for thiodisaccharide synthesis
10.1021/jo900514w · 2009 · External reference
Stereoselective synthesis of carbon-sulfur-bridged glycomimetics by photoinitiated thiol-ene coupling reactions
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Photoinitiated hydrothiolation of pyranoid exo-glycals: the d-galacto and d-xylo cases
10.1016/j.carres.2015.05.008 · 2015 · External reference
Thio-click reaction of 2-deoxy-exo-glycals towards new glycomimetics: stereoselective synthesis of C-2-deoxy-d-glycopyranosyl compounds
10.1039/c8nj06138f · 2019 · External reference
Synthesis of S-glycosyl amino acids and S-glycopeptides via photoinduced click thiol-ene coupling
10.1016/j.tetlet.2010.11.097 · 2011 · External reference
Photoinitiated thiol-ene reactions of various 2,3-unsaturated O-, C-, S- and N-glycosides-scope and limitations study
10.1002/asia.201901560 · 2020 · External reference
Thiyl glycosylation of olefinic proteins: S-linked glycoconjugate synthesis
10.1002/anie.200903135 · 2009 · External reference
Strong binding of C-glycosylic 1,2-Thiodisaccharides to Galectin-3 enthalpy-driven affinity enhancement by water-mediated hydrogen bonds
10.1021/acs.jmedchem.3c00882 · 2023 · External reference
Synthesis of thiodisaccharides related to 4-thiolactose. Specific structural modifications increase the inhibitory activity against E. Coli β-galactosidase
10.1039/d2ob02301f · 2023 · External reference
Thioglycoside functionalization via chemoselective phosphine acceleration of a photocatalytic thiol-ene reaction
10.1039/d5cc00131e · 2025 · External reference
Recent advance in the β-stereoselective synthesis of 2-deoxy glycosides
10.1002/ajoc.202400198 · 2024 · External reference
Iron-catalyzed aerobic hydration of Glycal: a route toward deoxy sugars/glycosides
10.1021/acs.joc.5c01820 · 2025 · External reference
Synthesis of 2-deoxy-C-glycosides via Lewis acid-mediated rearrangement of 2,3-anhydro-1-thiopyranosides
10.1039/c4qo00113c · 2014 · External reference
Glycosyl disulfides: importance, synthesis and application to chemical and biological systems
10.1039/d0ob02079f · 2021 · External reference
Preparation of glycosyl disulfides and sulfides via the formation of glycosyl Bunte salts as thiol surrogates
10.1016/j.tet.2021.132242 · 2024 · External reference
Towards more practical methods for the chemical synthesis of thioamides using sulfuration agents: a decade update
10.3390/molecules28083527 · 2023 · External reference
Amide bioisosteric replacement in the design and synthesis of quorum sensing modulators
10.1016/j.ejmech.2024.116525 · 2024 · External reference
Heterocyclic chemistry applied to the design of N-acyl homoserine lactone analogues as bacterial quorum sensing signals mimics
10.3390/molecules26175135 · 2021 · External reference
Thiooligosaccharide conjugate vaccines evoke antibodies specific for native antigens
10.1002/ange.200502179 · 2005 · External reference
Synthesis of multivalent S-glycoside analogs of a heparan sulfate sequence
10.1039/c9qo00581a · 2019 · External reference
Thiasugars: potential glycosidase inhibitors
10.2174/156802609787354270 · 2009 · External reference
5-Thio-d-mannose from the marine sponge Clathria pyramida (Lendenfeld). The first example of a naturally occurring 5-thiosugar
10.1039/c39870001200 · 1987 · External reference
Synthesis of the (1→6)-linked thiodisaccharide of galactofuranose: inhibitory activity against a β-galactofuranosidase
10.1016/j.bmc.2013.02.057 · 2013 · External reference
α-(1→2)-, α-(1→3)-, and α-(1→6)-linked thioglycosidic disaccharides: syntheses and anti-HIV testing of thiokojibiose octaacetate, thionigerose, and thioisomaltose
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Facile and versatile chemoenzymatic synthesis of enterobactin analogues and applications in bacterial detection
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