Research graph
References from Selectivity in CO2 Reduction: Beyond Two Electrons. Local targets link to admitted publications; unresolved targets remain external evidence.
Outer-Coordination-Sphere Interaction in a Molecular Iron Catalyst Allows Selective Methane Production from Carbon Monoxide
10.1021/acscatal.3c06112 · 2024 · External reference
Electrochemical Reduction of CO2 to CH3OH Catalyzed by an Iron Porphyrinoid
10.1021/jacs.4c08922 · 2025 · External reference
Synthesis of ethane from CO2 by a methyl transferase–inspired molecular catalyst
10.1073/pnas.2417764122 · 2025 · External reference
Proton and Electron Transfer Control of Selectivity in Electrochemical CO2 Reduction: Selective Reduction of CO2 to CO, CH4, and C2H6 Catalyzed by the Same Iron Porphyrin
10.1021/jacs.5c21473 · 2026 · External reference
Transition metal-based catalysts for the electrochemical CO(2) reduction: from atoms and molecules to nanostructured materials
10.1039/d0cs00835d · 2020 · External reference
Homogeneously Catalyzed Electroreduction of Carbon Dioxide-Methods, Mechanisms, and Catalysts
10.1021/acs.chemrev.7b00459 · 2018 · External reference
Biochemical and artificial pathways for the reduction of carbon dioxide, nitrite and the competing proton reduction: effect of 2(nd) sphere interactions in catalysis
10.1039/d0cs01405b · 2021 · External reference
Molecular catalysis of CO2 reduction: recent advances and perspectives in electrochemical and light-driven processes with selected Fe, Ni and Co aza macrocyclic and polypyridine complexes
10.1039/d0cs00218f · 2020 · External reference
First row transition metal dinuclear complexes for H2 production and CO2 reduction: from homogeneous to heterogeneous conditions
10.1016/j.ccr.2026.218063 · 2026 · External reference
Molecular Catalysts for the Reductive Homocoupling of CO2 towards C2+ Compounds
10.1002/anie.202200723 · 2022 · External reference
Heterogeneous molecular catalysts for Multi-Electron electrochemical CO2 reduction
10.1016/j.mattod.2025.08.014 · 2025 · External reference
Molecular copper catalysts for electro-reductive homocoupling of CO2 towards C2 compounds
10.1016/j.coelec.2024.101598 · 2025 · External reference
Carbon Dioxide Reduction Mediated by Iron Catalysts: Mechanism and Intermediates That Guide Selectivity
10.1021/acsomega.0c02786 · 2020 · External reference
Catalysis of the electrochemical reduction of carbon dioxide
10.1039/c2cs35360a · 2013 · External reference
Molecular engineering of metalloporphyrins and phthalocyanines for homogeneous and heterogeneous CO2 electroreduction
10.1039/d5sc07983g · 2026 · External reference
Current Issues in Molecular Catalysis Illustrated by Iron Porphyrins as Catalysts of the CO2-to-CO Electrochemical Conversion
10.1021/acs.accounts.5b00262 · 2015 · External reference
Across the Board: Rui Cao on Electrocatalytic CO2 Reduction
10.1002/cssc.202201788 · 2022 · External reference
Efficient and selective molecular catalyst for the CO2-to-CO electrochemical conversion in water
10.1073/pnas.1507063112 · 2015 · External reference
A Local Proton Source Enhances CO2 Electroreduction to CO by a Molecular Fe Catalyst
10.1126/science.1224581 · 2012 · External reference
An Iron Porphyrin Complex with Pendant Pyridine Substituents Facilitates Electrocatalytic CO2 Reduction via Second Coordination Sphere Effects
10.1002/cctc.202100625 · 2021 · External reference
Integrated molecular systems. Fixation of carbon monoxide on iron(I) in simple and superstructured porphyrins
10.1021/om00128a016 · 1985 · External reference
Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins. Synergistic Effect of Lewis Acid Cations
10.1021/jp9618486 · 1996 · External reference
Ultraefficient selective homogeneous catalysis of the electrochemical reduction of carbon dioxide by an iron(0) porphyrin associated with a weak Broensted acid cocatalyst
10.1021/ja00090a068 · 1994 · External reference
Examining the Importance of Hydrogen Bonding and Proton Transfer in Iron Porphyrin-Mediated Carbon Dioxide Upconversion
10.1021/acs.accounts.4c00329 · 2024 · External reference
Selectivity in Electrochemical CO2 Reduction
10.1021/acs.accounts.1c00678 · 2022 · External reference
Activating the Fe(I) State of Iron Porphyrinoid with Second-Sphere Proton Transfer Residues for Selective Reduction of CO2 to HCOOH via Fe(III/II)–COOH Intermediate(s)
10.1021/jacs.1c04392 · 2021 · External reference
Maximum and Comparative Efficiency Calculations for Integrated Capture and Electrochemical Conversion of CO2
10.1021/acsenergylett.3c02489 · 2024 · External reference
Further Understanding the Roles of Solvent, Brønsted Acids, and Hydrogen Bonding in Iron Porphyrin-Mediated Carbon Dioxide Reduction
10.1021/acs.inorgchem.3c01855 · 2023 · External reference
The Pattern of Hydroxyphenyl-Substitution Influences CO2 Reduction More Strongly than the Number of Hydroxyphenyl Groups in Iron-Porphyrin Electrocatalysts
10.1021/acscatal.2c06275 · 2023 · External reference
Understanding the Interplay of the Brønsted Acidity of Catalyst Ancillary Groups and the Solution Components in Iron-porphyrin-Mediated Carbon Dioxide Reduction
10.1021/jacs.3c10127 · 2024 · External reference
Second sphere control of CO2 reduction selectivity by iron porphyrins: The role of spin state
10.1016/j.jorganchem.2024.123439 · 2025 · External reference
Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels
10.1039/b804323j · 2009 · External reference
Molecular catalysis of the electrochemical and photochemical reduction of CO2 with Fe and Co metal based complexes. Recent advances
10.1016/j.ccr.2016.09.005 · 2017 · External reference
Recent advances in metalloporphyrin-based catalyst design towards carbon dioxide reduction: from bio-inspired second coordination sphere modifications to hierarchical architectures
10.1039/c9dt04709c · 2020 · External reference
Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels
10.1021/ar9001679 · 2009 · External reference
Electrochemical Carbon Dioxide Capture and Concentration
10.1021/acs.chemrev.2c00681 · 2023 · External reference
Selective Electrocatalytic Reduction of CO2 to HCO2–
10.1016/j.trechm.2020.02.001 · 2020 · External reference
Reversible and Selective CO2 to HCO2– Electrocatalysis near the Thermodynamic Potential
10.1002/anie.201913198 · 2020 · External reference
Intermediates Involved in the 2e–/2H+ Reduction of CO2 to CO by Iron(0) Porphyrin
10.1021/jacs.5b05992 · 2015 · External reference
A Single Iron Porphyrin Shows pH Dependent Switch between “Push” and “Pull” Effects in Electrochemical Oxygen Reduction
10.1021/acs.inorgchem.0c02408 · 2020 · External reference
Electrostatic versus Hydrogen Bonding Control of Selectivity in CO2 Reduction by Iron Porphyrins
10.1021/acscatal.5c00170 · 2025 · External reference
Electrochemistry of iron(I) porphyrins in the presence of carbon monoxide. Comparison with zinc porphyrins
10.1021/ic00087a038 · 1994 · External reference
Visible-light-driven methane formation from CO2 with a molecular iron catalyst
10.1038/nature23016 · 2017 · External reference
Single site porphyrine-like structures advantages over metals for selective electrochemical CO2 reduction
10.1016/j.cattod.2017.02.028 · 2017 · External reference
Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene–Isoquinoline Complex
10.1021/ja4074003 · 2013 · External reference
Electrocatalytic reduction of carbon dioxide to carbon monoxide and methane at an immobilized cobalt protoporphyrin
10.1038/ncomms9177 · 2015 · External reference
Electrocatalytic Reduction of CO2 to CH4 and CO in Aqueous Solution Using Pyridine-Porphyrins Immobilized onto Carbon Nanotubes
10.1021/acssuschemeng.0c02791 · 2020 · External reference
Rational Design of Mononuclear Iron Porphyrins for Facile and Selective 4e–/4H+ O2 Reduction: Activation of O–O Bond by 2nd Sphere Hydrogen Bonding
10.1021/jacs.8b02983 · 2018 · External reference
Aqueous Electrochemical Reduction of Carbon Dioxide and Carbon Monoxide into Methanol with Cobalt Phthalocyanine
10.1002/anie.201909257 · 2019 · External reference
Electrocatalytic CO2 to CO and Methanol Conversion Using a Molecular Cobalt Corrole Complex
10.1021/acscatal.5c02857 · 2025 · External reference
Molecular Electrochemical Catalysis of CO-to-Formaldehyde Conversion with a Cobalt Complex
10.1021/jacs.4c06878 · 2024 · External reference
In-situ spectroscopic probe of the intrinsic structure feature of single-atom center in electrochemical CO/CO2 reduction to methanol
10.1038/s41467-023-39153-6 · 2023 · External reference
CO2 electroreduction on Cu operates via an alternative chain growth mechanism to form C–C bonds at elevated temperature and pressure
10.1038/s41929-025-01451-1 · 2025 · External reference
Electrochemical Reduction of Carbon Dioxide to Ethane Using Nanostructured Cu2O-Derived Copper Catalyst and Palladium(II) Chloride
10.1021/acs.jpcc.5b09144 · 2015 · External reference
Electrochemical Reduction of CO2 to Ethane through Stabilization of an Ethoxy Intermediate
10.1002/anie.202004846 · 2020 · External reference
Efficient Electrocatalytic Reduction of CO2 to Ethane over Nitrogen-Doped Fe2O3
10.1021/jacs.2c05373 · 2022 · External reference
Highly selective photocatalytic reduction of CO2 to ethane over Au-O-Ce sites at micro-interface
10.1016/j.apcatb.2022.122020 · 2023 · External reference
High-rate solar-light photoconversion of CO2 to fuel: controllable transformation from C1 to C2 products
10.1039/c8ee00983j · 2018 · External reference
CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films
10.1021/ja3010978 · 2012 · External reference
Electrochemical CO2 reduction on Cu2O-derived copper nanoparticles: controlling the catalytic selectivity of hydrocarbons
10.1039/c4cp01520g · 2014 · External reference
Electrochemical conversion of CO2 to C2 hydrocarbons using different ex situ copper electrodeposits
10.1016/j.electacta.2013.04.015 · 2013 · External reference
Electrochemical Reduction of CO2 at Copper Nanofoams
10.1021/cs500522g · 2014 · External reference
Cobalamin-Dependent Methionine Synthase Is a Modular Protein with Distinct Regions for Binding Homocysteine, Methyltetrahydrofolate, Cobalamin, and Adenosylmethionine
10.1021/bi9705164 · 1997 · External reference
Aqueous Electrochemical Reduction of Carbon Dioxide and Carbon Monoxide into Methanol with Cobalt Phthalocyanine
10.1002/anie.201909257 · ExternalCitation · doi-reference
Reversible and Selective CO2 to HCO2– Electrocatalysis near the Thermodynamic Potential
10.1002/anie.201913198 · ExternalCitation · doi-reference
Electrochemical Reduction of CO2 to Ethane through Stabilization of an Ethoxy Intermediate
10.1002/anie.202004846 · ExternalCitation · doi-reference
Molecular Catalysts for the Reductive Homocoupling of CO2 towards C2+ Compounds
10.1002/anie.202200723 · ExternalCitation · doi-reference
An Iron Porphyrin Complex with Pendant Pyridine Substituents Facilitates Electrocatalytic CO2 Reduction via Second Coordination Sphere Effects
10.1002/cctc.202100625 · ExternalCitation · doi-reference
Across the Board: Rui Cao on Electrocatalytic CO2 Reduction
10.1002/cssc.202201788 · ExternalCitation · doi-reference
Highly selective photocatalytic reduction of CO2 to ethane over Au-O-Ce sites at micro-interface
10.1016/j.apcatb.2022.122020 · ExternalCitation · doi-reference
Single site porphyrine-like structures advantages over metals for selective electrochemical CO2 reduction
10.1016/j.cattod.2017.02.028 · ExternalCitation · doi-reference
Molecular catalysis of the electrochemical and photochemical reduction of CO2 with Fe and Co metal based complexes. Recent advances
10.1016/j.ccr.2016.09.005 · ExternalCitation · doi-reference
First row transition metal dinuclear complexes for H2 production and CO2 reduction: from homogeneous to heterogeneous conditions
10.1016/j.ccr.2026.218063 · ExternalCitation · doi-reference
Molecular copper catalysts for electro-reductive homocoupling of CO2 towards C2 compounds
10.1016/j.coelec.2024.101598 · ExternalCitation · doi-reference
Electrochemical conversion of CO2 to C2 hydrocarbons using different ex situ copper electrodeposits
10.1016/j.electacta.2013.04.015 · ExternalCitation · doi-reference
Second sphere control of CO2 reduction selectivity by iron porphyrins: The role of spin state
10.1016/j.jorganchem.2024.123439 · ExternalCitation · doi-reference
Heterogeneous molecular catalysts for Multi-Electron electrochemical CO2 reduction
10.1016/j.mattod.2025.08.014 · ExternalCitation · doi-reference
Selective Electrocatalytic Reduction of CO2 to HCO2–
10.1016/j.trechm.2020.02.001 · ExternalCitation · doi-reference
Selectivity in Electrochemical CO2 Reduction
10.1021/acs.accounts.1c00678 · ExternalCitation · doi-reference
Examining the Importance of Hydrogen Bonding and Proton Transfer in Iron Porphyrin-Mediated Carbon Dioxide Upconversion
10.1021/acs.accounts.4c00329 · ExternalCitation · doi-reference
Current Issues in Molecular Catalysis Illustrated by Iron Porphyrins as Catalysts of the CO2-to-CO Electrochemical Conversion
10.1021/acs.accounts.5b00262 · ExternalCitation · doi-reference
Electrochemical Carbon Dioxide Capture and Concentration
10.1021/acs.chemrev.2c00681 · ExternalCitation · doi-reference
Homogeneously Catalyzed Electroreduction of Carbon Dioxide-Methods, Mechanisms, and Catalysts
10.1021/acs.chemrev.7b00459 · ExternalCitation · doi-reference
A Single Iron Porphyrin Shows pH Dependent Switch between “Push” and “Pull” Effects in Electrochemical Oxygen Reduction
10.1021/acs.inorgchem.0c02408 · ExternalCitation · doi-reference
Further Understanding the Roles of Solvent, Brønsted Acids, and Hydrogen Bonding in Iron Porphyrin-Mediated Carbon Dioxide Reduction
10.1021/acs.inorgchem.3c01855 · ExternalCitation · doi-reference
Electrochemical Reduction of Carbon Dioxide to Ethane Using Nanostructured Cu2O-Derived Copper Catalyst and Palladium(II) Chloride
10.1021/acs.jpcc.5b09144 · ExternalCitation · doi-reference
The Pattern of Hydroxyphenyl-Substitution Influences CO2 Reduction More Strongly than the Number of Hydroxyphenyl Groups in Iron-Porphyrin Electrocatalysts
10.1021/acscatal.2c06275 · ExternalCitation · doi-reference
Outer-Coordination-Sphere Interaction in a Molecular Iron Catalyst Allows Selective Methane Production from Carbon Monoxide
10.1021/acscatal.3c06112 · ExternalCitation · doi-reference
Electrostatic versus Hydrogen Bonding Control of Selectivity in CO2 Reduction by Iron Porphyrins
10.1021/acscatal.5c00170 · ExternalCitation · doi-reference
Electrocatalytic CO2 to CO and Methanol Conversion Using a Molecular Cobalt Corrole Complex
10.1021/acscatal.5c02857 · ExternalCitation · doi-reference
Maximum and Comparative Efficiency Calculations for Integrated Capture and Electrochemical Conversion of CO2
10.1021/acsenergylett.3c02489 · ExternalCitation · doi-reference
Carbon Dioxide Reduction Mediated by Iron Catalysts: Mechanism and Intermediates That Guide Selectivity
10.1021/acsomega.0c02786 · ExternalCitation · doi-reference
Electrocatalytic Reduction of CO2 to CH4 and CO in Aqueous Solution Using Pyridine-Porphyrins Immobilized onto Carbon Nanotubes
10.1021/acssuschemeng.0c02791 · ExternalCitation · doi-reference
Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels
10.1021/ar9001679 · ExternalCitation · doi-reference
Cobalamin-Dependent Methionine Synthase Is a Modular Protein with Distinct Regions for Binding Homocysteine, Methyltetrahydrofolate, Cobalamin, and Adenosylmethionine
10.1021/bi9705164 · ExternalCitation · doi-reference
Electrochemical Reduction of CO2 at Copper Nanofoams
10.1021/cs500522g · ExternalCitation · doi-reference
Electrochemistry of iron(I) porphyrins in the presence of carbon monoxide. Comparison with zinc porphyrins
10.1021/ic00087a038 · ExternalCitation · doi-reference
Ultraefficient selective homogeneous catalysis of the electrochemical reduction of carbon dioxide by an iron(0) porphyrin associated with a weak Broensted acid cocatalyst
10.1021/ja00090a068 · ExternalCitation · doi-reference
CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films
10.1021/ja3010978 · ExternalCitation · doi-reference
Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene–Isoquinoline Complex
10.1021/ja4074003 · ExternalCitation · doi-reference
Activating the Fe(I) State of Iron Porphyrinoid with Second-Sphere Proton Transfer Residues for Selective Reduction of CO2 to HCOOH via Fe(III/II)–COOH Intermediate(s)
10.1021/jacs.1c04392 · ExternalCitation · doi-reference
Efficient Electrocatalytic Reduction of CO2 to Ethane over Nitrogen-Doped Fe2O3
10.1021/jacs.2c05373 · ExternalCitation · doi-reference
Understanding the Interplay of the Brønsted Acidity of Catalyst Ancillary Groups and the Solution Components in Iron-porphyrin-Mediated Carbon Dioxide Reduction
10.1021/jacs.3c10127 · ExternalCitation · doi-reference
Molecular Electrochemical Catalysis of CO-to-Formaldehyde Conversion with a Cobalt Complex
10.1021/jacs.4c06878 · ExternalCitation · doi-reference
Electrochemical Reduction of CO2 to CH3OH Catalyzed by an Iron Porphyrinoid
10.1021/jacs.4c08922 · ExternalCitation · doi-reference
Intermediates Involved in the 2e–/2H+ Reduction of CO2 to CO by Iron(0) Porphyrin
10.1021/jacs.5b05992 · ExternalCitation · doi-reference
Proton and Electron Transfer Control of Selectivity in Electrochemical CO2 Reduction: Selective Reduction of CO2 to CO, CH4, and C2H6 Catalyzed by the Same Iron Porphyrin
10.1021/jacs.5c21473 · ExternalCitation · doi-reference
Rational Design of Mononuclear Iron Porphyrins for Facile and Selective 4e–/4H+ O2 Reduction: Activation of O–O Bond by 2nd Sphere Hydrogen Bonding
10.1021/jacs.8b02983 · ExternalCitation · doi-reference
Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins. Synergistic Effect of Lewis Acid Cations
10.1021/jp9618486 · ExternalCitation · doi-reference
Integrated molecular systems. Fixation of carbon monoxide on iron(I) in simple and superstructured porphyrins
10.1021/om00128a016 · ExternalCitation · doi-reference
Visible-light-driven methane formation from CO2 with a molecular iron catalyst
10.1038/nature23016 · ExternalCitation · doi-reference
Electrocatalytic reduction of carbon dioxide to carbon monoxide and methane at an immobilized cobalt protoporphyrin
10.1038/ncomms9177 · ExternalCitation · doi-reference
In-situ spectroscopic probe of the intrinsic structure feature of single-atom center in electrochemical CO/CO2 reduction to methanol
10.1038/s41467-023-39153-6 · ExternalCitation · doi-reference
CO2 electroreduction on Cu operates via an alternative chain growth mechanism to form C–C bonds at elevated temperature and pressure
10.1038/s41929-025-01451-1 · ExternalCitation · doi-reference
Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels
10.1039/b804323j · ExternalCitation · doi-reference
Catalysis of the electrochemical reduction of carbon dioxide
10.1039/c2cs35360a · ExternalCitation · doi-reference
Electrochemical CO2 reduction on Cu2O-derived copper nanoparticles: controlling the catalytic selectivity of hydrocarbons
10.1039/c4cp01520g · ExternalCitation · doi-reference
High-rate solar-light photoconversion of CO2 to fuel: controllable transformation from C1 to C2 products
10.1039/c8ee00983j · ExternalCitation · doi-reference
Recent advances in metalloporphyrin-based catalyst design towards carbon dioxide reduction: from bio-inspired second coordination sphere modifications to hierarchical architectures
10.1039/c9dt04709c · ExternalCitation · doi-reference
Molecular catalysis of CO2 reduction: recent advances and perspectives in electrochemical and light-driven processes with selected Fe, Ni and Co aza macrocyclic and polypyridine complexes
10.1039/d0cs00218f · ExternalCitation · doi-reference
Transition metal-based catalysts for the electrochemical CO(2) reduction: from atoms and molecules to nanostructured materials
10.1039/d0cs00835d · ExternalCitation · doi-reference
Biochemical and artificial pathways for the reduction of carbon dioxide, nitrite and the competing proton reduction: effect of 2(nd) sphere interactions in catalysis
10.1039/d0cs01405b · ExternalCitation · doi-reference
Molecular engineering of metalloporphyrins and phthalocyanines for homogeneous and heterogeneous CO2 electroreduction
10.1039/d5sc07983g · ExternalCitation · doi-reference
Efficient and selective molecular catalyst for the CO2-to-CO electrochemical conversion in water
10.1073/pnas.1507063112 · ExternalCitation · doi-reference
Synthesis of ethane from CO2 by a methyl transferase–inspired molecular catalyst
10.1073/pnas.2417764122 · ExternalCitation · doi-reference
A Local Proton Source Enhances CO2 Electroreduction to CO by a Molecular Fe Catalyst
10.1126/science.1224581 · ExternalCitation · doi-reference
