Research graph
References from Asymmetric Copper-Catalyzed Propargylation of 5-Aminopyrazoles with Propargylic Acetates. Local targets link to admitted publications; unresolved targets remain external evidence.
Unresolved reference
1978 · External reference
Unresolved reference
1991 · External reference
Rhenium-Catalyzed Aromatic Propargylation
10.1021/ol049649p · 2004 · External reference
Rhenium-Catalyzed Coupling of Propargyl Alcohols and Allyl Silanes
10.1021/ja039124c · 2003 · External reference
A General Strategy Using η2-Co2(CO)6 Acetylene Complexes for the Synthesis of the Enediyne Antitumor Agents Esperamicin, Calicheamicin, Dynemicin and Neocarzinostatin
10.1016/s0040-4020(01)80626-8 · 1994 · External reference
Highly Stereocontrolled Total Synthesis of (+)-Bengamide E
10.1039/p19950002849 · 1995 · External reference
Formal Total Syntheses of the β-Lactam Antibiotics Thienamycin and PS-5
10.1021/jo952092u · 1996 · External reference
Tandem Use of Cobalt-Mediated Reactions to Synthesize (+)-Epoxydictymene, a Diterpene Containing a trans-Fused 5–5 Ring System
10.1021/ja970022u · 1997 · External reference
Ni-Catalyzed Regioselective Hydrometalative Cyclization of Alkynyl Cyclobutanones to Bicyclo[2.1.1]hexanes
10.31635/ccschem.025.202506260 · 2026 · External reference
Catalyzed Propargylic Substitution
10.1002/ejoc.200900877 · 2009 · External reference
Transition-Metal-Catalyzed Propargylic Substitution
10.1002/anie.200804114 · 2009 · External reference
Catalytic Propargylic Substitution Reactions
10.1002/cctc.200900214 · 2009 · External reference
Catalytic Asymmetric Propargylation
10.1021/cr100284m · 2011 · External reference
Ruthenium-Catalyzed Asymmetric Propargylic Substitution Reactions of Propargylic Alcohols with Acetone
10.1002/anie.200502981 · 2005 · External reference
Synthesis of Diruthenium Complexes Containing Chiral Thiolate-Bridged Ligands and Their Application to Catalytic Propargylic Alkylation of Propargylic Alcohols with Acetone
10.1021/om020814j · 2003 · External reference
Enantioselective Copper-Catalyzed Propargylic Amination
10.1002/anie.200705264 · 2008 · External reference
Enantioselective Copper-Catalyzed Propargylic Substitution: Synthetic Scope Study and Application in Formal Total Syntheses of (+)-Anisomycin and (−)-Cytoxazone
10.1002/chem.201003727 · 2011 · External reference
Copper(I)-Catalyzed Amination of Propargyl Esters: Selective Synthesis of Propargylamines, 1-Alken-3-ylamines, and (Z)-Allylamines
10.1021/jo00088a004 · 1994 · External reference
Enantioselective Propargylic Amination and Related Tandem Sequences to α-Tertiary Ethynylamines and Azacycles
10.1038/s41557-024-01479-z · 2024 · External reference
Trifluoroethanol-Assisted Asymmetric Propargylic Hydrazination to α-Tertiary Ethynylhydrazines Enabled by Sterically Confined Pyridinebisoxazolines
10.1038/s41467-025-59845-5 · 2025 · External reference
Tandem Asymmetric Propargylic Amination/Carboxylative Cyclization Reaction to Chiral 5-methylidene-2-oxazolidinones Using CO2 as C1 Synthon
10.1007/s11426-024-2346-4 · 2025 · External reference
Propargylic Amination Enabled the Access to Enantioenriched Acyclic α-Quaternary α-Amino Ketones
10.1021/jacs.1c03182 · 2021 · External reference
Access to Enantioenriched Dihydroquinoxalinones via Cu-Catalyzed Propargylic Substitution
10.1039/d4qo00080c · 2024 · External reference
Well-defined chiral dinuclear copper complexes in enantioselective propargylic substitution: For a long-standing supposition on binuclear mechanism
10.1016/j.chempr.2023.09.006 · 2024 · External reference
Chiral Tridentate P,N,N Ligands for Highly Enantioselective Copper-Catalyzed Propargylic Amination with Both Primary and Secondary Amines as Nucleophiles
10.1002/adsc.201200589 · 2012 · External reference
Enantioselective propargylic substitution reactions via transition metal-allenylidene complexes as key intermediates
10.1016/j.cocr.2024.100003 · 2025 · External reference
Enantioselectivity in Transition Metal Catalyzed Propargylic Substitution Reactions: A Theoretical Perspective
10.1002/chem.70775 · 2026 · External reference
Copper-catalyzed convergent regio- and enantioselective alkynylallylic substitution
10.1038/s44160-022-00176-4 · 2023 · External reference
Asymmetric Substitution by Alkynyl Copper Driven Dearomatization and Rearomatization
10.1002/anie.202314517 · 2023 · External reference
Asymmetric Multicomponent Propargylations via Carbon Dioxide Shuttling and Fixation
10.1021/acscatal.4c02333 · 2024 · External reference
Asymmetric Remote Leaving Group-Promoted Propargylic Substitution
10.1021/acscatal.5c01798 · 2025 · External reference
Copper-Catalyzed Intermolecular Asymmetric Propargylic Dearomatization of Indoles
10.1002/anie.201503042 · 2015 · External reference
Desilylation-Activated Propargylic Transformation: Enantioselective Copper-Catalyzed [3 + 2] Cycloaddition of Propargylic Esters with β-Naphthol or Phenol Derivatives
10.1002/anie.201510793 · 2016 · External reference
Construction of Chiral Tri- and Tetraarylmethanes Bearing Quaternary Carbon Centers: Copper-Catalyzed Enantioselective Propargylation of Indoles with Propargylic Esters
10.1002/anie.201604182 · 2016 · External reference
Highly Enantioselective Catalytic Vinylogous Propargylation of Coumarins Yields a Class of Autophagy Inhibitors
10.1002/anie.201706005 · 2017 · External reference
Enantioconvergent Copper Catalysis: In Situ Generation of the Chiral Phosphorus Ylide and Its Wittig Reactions
10.1021/jacs.7b08207 · 2017 · External reference
Diastereo- and Enantioselective Propargylation of 5H-Thiazol-4-ones and 5H-Oxazol-4-ones as Enabled by Cu/Zn and Cu/Ti Catalysis
10.1002/anie.201809391 · 2018 · External reference
Copper-Catalyzed Enantioselective Propargylic Etherification of Propargylic Esters with Alcohols
10.1021/jacs.5b00004 · 2015 · External reference
Enantioselective Copper-Catalyzed Propargylic Etherification of Propargylic Esters with Phenols Promoted by Inorganic Base Additives
10.1002/adsc.201600284 · 2016 · External reference
Copper- and Borinic Acid-Catalyzed Propargylic Etherification of Propargylic Carbonates with Benzyl Alcohols
10.1246/cl.180123 · 2018 · External reference
Copper-Catalyzed Enantioselective Construction of Tertiary Propargylic Sulfones
10.1002/anie.201814242 · 2019 · External reference
Total Synthesis of (−)-Rhazinilam and Formal Synthesis of (+)-Eburenine and (+)-Aspidospermidine: Asymmetric Cu-Catalyzed Propargylic Substitution
10.1021/acs.orglett.7b02619 · 2017 · External reference
Divergent Synthesis of Polycyclic Indolines: Copper-Catalyzed Cascade Reactions of Propargylic Carbamates and Indoles
10.1021/acs.orglett.7b01903 · 2017 · External reference
Copper-Catalyzed Asymmetric Yne-Allylic Substitution Using Electron-Rich Arenes
10.1021/acscatal.3c06146 · 2024 · External reference
Copper-Catalyzed Remote Regio- and Enantioselective Yne-Allylic Substitution of Coumarins
10.1021/acs.orglett.4c02012 · 2024 · External reference
Copper-Catalyzed Asymmetric Propargylic Alkylation with Oxindoles: Diastereo- and Enantioselective Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters
10.1021/acs.orglett.9b04621 · 2020 · External reference
Copper-Catalyzed Asymmetric Propargylic Substitution of 2,2,2-Trifluoroethylisoxazoles with Propargylic Alcohol Derivatives
10.1021/acs.orglett.3c01521 · 2023 · External reference
Asymmetric Catalytic [4 + 2] Cycloaddition via Cu-Allenylidene Intermediate: Stereoselective Synthesis of Tetrahydroquinolines Fused with a γ-Lactone Moiety
10.1021/acs.orglett.8b00253 · 2018 · External reference
Ruthenium-Catalyzed Enantioselective Propargylation of Aromatic Compounds with Propargylic Alcohols via Allenylidene Intermediates
10.1002/anie.200701261 · 2007 · External reference
Copper-Catalyzed Asymmetric Propargylation of Indolizines
10.1021/acs.orglett.9b03032 · 2019 · External reference
Organocatalytic Enantioselective Aminoalkylation of 5-Aminopyrazole Derivatives with Cyclic Imines
10.1002/ejoc.202001314 · 2020 · External reference
N-Heterocyclic Carbene-Catalyzed [3 + 3] Annulation of 5-Aminopyrazoles with Enals: Enantioselective Synthesis of Pyrazolo[3,4-b]pyridones
10.1021/acs.joc.3c00793 · 2023 · External reference
Enantioselective Synthesis of Dihydropyrazolo[3,4-b]pyridin-6-ones via N-Heterocyclic Carbene Catalyzed [3 + 3] Cycloaddition of α-Bromoenals with 5-Aminopyrazoles
10.1002/adsc.202201335 · 2023 · External reference
Asymmetric Aza-Friedel-Crafts Reaction of Cyclic Ketimines with 5-Aminopyrazole Derivatives: Expedient Access to Pyrazole-Based C2-Quaternary Indolin-3-ones
10.1002/chem.202203914 · 2023 · External reference
Asymmetric Synthesis of Atropisomeric Arylpyrazoles via Direct Arylation of 5-Aminopyrazoles with Naphthoquinones
10.1039/d4ob00514g · 2024 · External reference
Synthesis of Heterotriarylmethanes Catalyzed by Chiral Phosphoric Acid with 5-Aminopyrazole and Azadiene
10.1021/acs.joc.5c02564 · 2026 · External reference
Asymmetric Synthesis of Polycyclic Heterocyclic Compounds via Friedel-Crafts Reaction/Cyclization Reaction Catalyzed by Nickel Catalyst
10.1021/acs.orglett.4c03674 · 2024 · External reference
Chiral Phosphoric Acid-Catalyzed Asymmetric Synthesis of Axially Chiral Arylpyrazole
10.1021/acs.orglett.4c03996 · 2025 · External reference
Bipyridine-N,N′-Dioxides Catalysts: Design, Synthesis, and Application in Asymmetric Synthesis of 1H-Pyrazolo[3,4-b]pyridine Analogues
10.1021/acs.orglett.4c00515 · 2024 · External reference
Asymmetric Synthesis of 1H-Pyrazolo[3,4-b]pyridine Analogues Catalyzed by Chiral-at-Metal Rh(III) Complexes
10.1039/d4qo01100g · 2024 · External reference
Design, Synthesis and Application of Bipyridine-N,N′-Dioxide Catalysts in Asymmetric Synthesis of Chiral Cyclopropanes
10.1039/d4qo01532k · 2024 · External reference
Asymmetric Synthesis of Chiral Cyclopropanes from Vinyl Sulfoxonium Ylides Catalyzed by a Chiral-at-Metal Rh(III) Complex
10.1021/acs.orglett.4c03051 · 2024 · External reference
Copper-Catalyzed Asymmetric Propargylation of 5-Aminopyrazoles
10.1021/acs.orglett.6c01240 · 2026 · External reference
Copper-Catalyzed Enantioselective Propargylic Amination of Propargylic Esters with Amines: Copper–Allenylidene Complexes as Key Intermediates
10.1021/ja1047494 · 2010 · External reference
Chiral Tridentate P,N,N Ligands for Highly Enantioselective Copper-Catalyzed Propargylic Amination with Both Primary and Secondary Amines as Nucleophiles
10.1002/adsc.201200589 · ExternalCitation · doi-reference
Enantioselective Copper-Catalyzed Propargylic Etherification of Propargylic Esters with Phenols Promoted by Inorganic Base Additives
10.1002/adsc.201600284 · ExternalCitation · doi-reference
Enantioselective Synthesis of Dihydropyrazolo[3,4-b]pyridin-6-ones via N-Heterocyclic Carbene Catalyzed [3 + 3] Cycloaddition of α-Bromoenals with 5-Aminopyrazoles
10.1002/adsc.202201335 · ExternalCitation · doi-reference
Ruthenium-Catalyzed Asymmetric Propargylic Substitution Reactions of Propargylic Alcohols with Acetone
10.1002/anie.200502981 · ExternalCitation · doi-reference
Ruthenium-Catalyzed Enantioselective Propargylation of Aromatic Compounds with Propargylic Alcohols via Allenylidene Intermediates
10.1002/anie.200701261 · ExternalCitation · doi-reference
Enantioselective Copper-Catalyzed Propargylic Amination
10.1002/anie.200705264 · ExternalCitation · doi-reference
Transition-Metal-Catalyzed Propargylic Substitution
10.1002/anie.200804114 · ExternalCitation · doi-reference
Copper-Catalyzed Intermolecular Asymmetric Propargylic Dearomatization of Indoles
10.1002/anie.201503042 · ExternalCitation · doi-reference
Desilylation-Activated Propargylic Transformation: Enantioselective Copper-Catalyzed [3 + 2] Cycloaddition of Propargylic Esters with β-Naphthol or Phenol Derivatives
10.1002/anie.201510793 · ExternalCitation · doi-reference
Construction of Chiral Tri- and Tetraarylmethanes Bearing Quaternary Carbon Centers: Copper-Catalyzed Enantioselective Propargylation of Indoles with Propargylic Esters
10.1002/anie.201604182 · ExternalCitation · doi-reference
Highly Enantioselective Catalytic Vinylogous Propargylation of Coumarins Yields a Class of Autophagy Inhibitors
10.1002/anie.201706005 · ExternalCitation · doi-reference
Diastereo- and Enantioselective Propargylation of 5H-Thiazol-4-ones and 5H-Oxazol-4-ones as Enabled by Cu/Zn and Cu/Ti Catalysis
10.1002/anie.201809391 · ExternalCitation · doi-reference
Copper-Catalyzed Enantioselective Construction of Tertiary Propargylic Sulfones
10.1002/anie.201814242 · ExternalCitation · doi-reference
Asymmetric Substitution by Alkynyl Copper Driven Dearomatization and Rearomatization
10.1002/anie.202314517 · ExternalCitation · doi-reference
Catalytic Propargylic Substitution Reactions
10.1002/cctc.200900214 · ExternalCitation · doi-reference
Enantioselective Copper-Catalyzed Propargylic Substitution: Synthetic Scope Study and Application in Formal Total Syntheses of (+)-Anisomycin and (−)-Cytoxazone
10.1002/chem.201003727 · ExternalCitation · doi-reference
Asymmetric Aza-Friedel-Crafts Reaction of Cyclic Ketimines with 5-Aminopyrazole Derivatives: Expedient Access to Pyrazole-Based C2-Quaternary Indolin-3-ones
10.1002/chem.202203914 · ExternalCitation · doi-reference
Enantioselectivity in Transition Metal Catalyzed Propargylic Substitution Reactions: A Theoretical Perspective
10.1002/chem.70775 · ExternalCitation · doi-reference
Catalyzed Propargylic Substitution
10.1002/ejoc.200900877 · ExternalCitation · doi-reference
Organocatalytic Enantioselective Aminoalkylation of 5-Aminopyrazole Derivatives with Cyclic Imines
10.1002/ejoc.202001314 · ExternalCitation · doi-reference
Tandem Asymmetric Propargylic Amination/Carboxylative Cyclization Reaction to Chiral 5-methylidene-2-oxazolidinones Using CO2 as C1 Synthon
10.1007/s11426-024-2346-4 · ExternalCitation · doi-reference
Well-defined chiral dinuclear copper complexes in enantioselective propargylic substitution: For a long-standing supposition on binuclear mechanism
10.1016/j.chempr.2023.09.006 · ExternalCitation · doi-reference
Enantioselective propargylic substitution reactions via transition metal-allenylidene complexes as key intermediates
10.1016/j.cocr.2024.100003 · ExternalCitation · doi-reference
A General Strategy Using η2-Co2(CO)6 Acetylene Complexes for the Synthesis of the Enediyne Antitumor Agents Esperamicin, Calicheamicin, Dynemicin and Neocarzinostatin
10.1016/s0040-4020(01)80626-8 · ExternalCitation · doi-reference
N-Heterocyclic Carbene-Catalyzed [3 + 3] Annulation of 5-Aminopyrazoles with Enals: Enantioselective Synthesis of Pyrazolo[3,4-b]pyridones
10.1021/acs.joc.3c00793 · ExternalCitation · doi-reference
Synthesis of Heterotriarylmethanes Catalyzed by Chiral Phosphoric Acid with 5-Aminopyrazole and Azadiene
10.1021/acs.joc.5c02564 · ExternalCitation · doi-reference
Copper-Catalyzed Asymmetric Propargylic Substitution of 2,2,2-Trifluoroethylisoxazoles with Propargylic Alcohol Derivatives
10.1021/acs.orglett.3c01521 · ExternalCitation · doi-reference
Bipyridine-N,N′-Dioxides Catalysts: Design, Synthesis, and Application in Asymmetric Synthesis of 1H-Pyrazolo[3,4-b]pyridine Analogues
10.1021/acs.orglett.4c00515 · ExternalCitation · doi-reference
Copper-Catalyzed Remote Regio- and Enantioselective Yne-Allylic Substitution of Coumarins
10.1021/acs.orglett.4c02012 · ExternalCitation · doi-reference
Asymmetric Synthesis of Chiral Cyclopropanes from Vinyl Sulfoxonium Ylides Catalyzed by a Chiral-at-Metal Rh(III) Complex
10.1021/acs.orglett.4c03051 · ExternalCitation · doi-reference
Asymmetric Synthesis of Polycyclic Heterocyclic Compounds via Friedel-Crafts Reaction/Cyclization Reaction Catalyzed by Nickel Catalyst
10.1021/acs.orglett.4c03674 · ExternalCitation · doi-reference
Chiral Phosphoric Acid-Catalyzed Asymmetric Synthesis of Axially Chiral Arylpyrazole
10.1021/acs.orglett.4c03996 · ExternalCitation · doi-reference
Copper-Catalyzed Asymmetric Propargylation of 5-Aminopyrazoles
10.1021/acs.orglett.6c01240 · ExternalCitation · doi-reference
Divergent Synthesis of Polycyclic Indolines: Copper-Catalyzed Cascade Reactions of Propargylic Carbamates and Indoles
10.1021/acs.orglett.7b01903 · ExternalCitation · doi-reference
Total Synthesis of (−)-Rhazinilam and Formal Synthesis of (+)-Eburenine and (+)-Aspidospermidine: Asymmetric Cu-Catalyzed Propargylic Substitution
10.1021/acs.orglett.7b02619 · ExternalCitation · doi-reference
Asymmetric Catalytic [4 + 2] Cycloaddition via Cu-Allenylidene Intermediate: Stereoselective Synthesis of Tetrahydroquinolines Fused with a γ-Lactone Moiety
10.1021/acs.orglett.8b00253 · ExternalCitation · doi-reference
Copper-Catalyzed Asymmetric Propargylation of Indolizines
10.1021/acs.orglett.9b03032 · ExternalCitation · doi-reference
Copper-Catalyzed Asymmetric Propargylic Alkylation with Oxindoles: Diastereo- and Enantioselective Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters
10.1021/acs.orglett.9b04621 · ExternalCitation · doi-reference
Copper-Catalyzed Asymmetric Yne-Allylic Substitution Using Electron-Rich Arenes
10.1021/acscatal.3c06146 · ExternalCitation · doi-reference
Asymmetric Multicomponent Propargylations via Carbon Dioxide Shuttling and Fixation
10.1021/acscatal.4c02333 · ExternalCitation · doi-reference
Asymmetric Remote Leaving Group-Promoted Propargylic Substitution
10.1021/acscatal.5c01798 · ExternalCitation · doi-reference
Catalytic Asymmetric Propargylation
10.1021/cr100284m · ExternalCitation · doi-reference
Rhenium-Catalyzed Coupling of Propargyl Alcohols and Allyl Silanes
10.1021/ja039124c · ExternalCitation · doi-reference
Copper-Catalyzed Enantioselective Propargylic Amination of Propargylic Esters with Amines: Copper–Allenylidene Complexes as Key Intermediates
10.1021/ja1047494 · ExternalCitation · doi-reference
Tandem Use of Cobalt-Mediated Reactions to Synthesize (+)-Epoxydictymene, a Diterpene Containing a trans-Fused 5–5 Ring System
10.1021/ja970022u · ExternalCitation · doi-reference
Propargylic Amination Enabled the Access to Enantioenriched Acyclic α-Quaternary α-Amino Ketones
10.1021/jacs.1c03182 · ExternalCitation · doi-reference
Copper-Catalyzed Enantioselective Propargylic Etherification of Propargylic Esters with Alcohols
10.1021/jacs.5b00004 · ExternalCitation · doi-reference
Enantioconvergent Copper Catalysis: In Situ Generation of the Chiral Phosphorus Ylide and Its Wittig Reactions
10.1021/jacs.7b08207 · ExternalCitation · doi-reference
Copper(I)-Catalyzed Amination of Propargyl Esters: Selective Synthesis of Propargylamines, 1-Alken-3-ylamines, and (Z)-Allylamines
10.1021/jo00088a004 · ExternalCitation · doi-reference
Formal Total Syntheses of the β-Lactam Antibiotics Thienamycin and PS-5
10.1021/jo952092u · ExternalCitation · doi-reference
Rhenium-Catalyzed Aromatic Propargylation
10.1021/ol049649p · ExternalCitation · doi-reference
Synthesis of Diruthenium Complexes Containing Chiral Thiolate-Bridged Ligands and Their Application to Catalytic Propargylic Alkylation of Propargylic Alcohols with Acetone
10.1021/om020814j · ExternalCitation · doi-reference
Trifluoroethanol-Assisted Asymmetric Propargylic Hydrazination to α-Tertiary Ethynylhydrazines Enabled by Sterically Confined Pyridinebisoxazolines
10.1038/s41467-025-59845-5 · ExternalCitation · doi-reference
Enantioselective Propargylic Amination and Related Tandem Sequences to α-Tertiary Ethynylamines and Azacycles
10.1038/s41557-024-01479-z · ExternalCitation · doi-reference
Copper-catalyzed convergent regio- and enantioselective alkynylallylic substitution
10.1038/s44160-022-00176-4 · ExternalCitation · doi-reference
Asymmetric Synthesis of Atropisomeric Arylpyrazoles via Direct Arylation of 5-Aminopyrazoles with Naphthoquinones
10.1039/d4ob00514g · ExternalCitation · doi-reference
Access to Enantioenriched Dihydroquinoxalinones via Cu-Catalyzed Propargylic Substitution
10.1039/d4qo00080c · ExternalCitation · doi-reference
Asymmetric Synthesis of 1H-Pyrazolo[3,4-b]pyridine Analogues Catalyzed by Chiral-at-Metal Rh(III) Complexes
10.1039/d4qo01100g · ExternalCitation · doi-reference
Design, Synthesis and Application of Bipyridine-N,N′-Dioxide Catalysts in Asymmetric Synthesis of Chiral Cyclopropanes
10.1039/d4qo01532k · ExternalCitation · doi-reference
Highly Stereocontrolled Total Synthesis of (+)-Bengamide E
10.1039/p19950002849 · ExternalCitation · doi-reference
Copper- and Borinic Acid-Catalyzed Propargylic Etherification of Propargylic Carbonates with Benzyl Alcohols
10.1246/cl.180123 · ExternalCitation · doi-reference
Ni-Catalyzed Regioselective Hydrometalative Cyclization of Alkynyl Cyclobutanones to Bicyclo[2.1.1]hexanes
10.31635/ccschem.025.202506260 · ExternalCitation · doi-reference