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References from DiploPhos: A Hemilabile Bisphosphine for Sterically Hindered Ni-Catalyzed Suzuki–Miyaura Couplings. Local targets link to admitted publications; unresolved targets remain external evidence.
Palladium-Catalyzed Suzuki–Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands
10.1021/ar800036s · 2008 · External reference
Palladium-Catalyzed Coupling Reactions of Aryl Chlorides
10.1002/1521-3773(20021115)41:22<4176::aid-anie4176>3.0.co;2-u · 2002 · External reference
Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals
10.1021/cr100346g · 2011 · External reference
Analysis of Past and Present Synthetic Methodologies on Medicinal Chemistry: Where Have All the New Reactions Gone?
10.1021/acs.jmedchem.5b01409 · 2016 · External reference
Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling Facilitated by a Weak Amine Base with Water as a Cosolvent
10.1021/acs.organomet.2c00197 · 2022 · External reference
ProPhos: A Ligand for Promoting Nickel-Catalyzed Suzuki-Miyaura Coupling Inspired by Mechanistic Insights into Transmetalation
10.1021/jacs.4c00370 · 2024 · External reference
Process-Ready Nickel-Catalyzed Suzuki–Miyaura Coupling Enabled by tri-ProPhos
10.1021/acscatal.5c07157 · 2025 · External reference
Nickel Bromide Catalyzed Ligand-Free and Activator-less Suzuki Coupling Reactions
10.1002/cctc.202200440 · 2022 · External reference
Suzuki Cross-Coupling of Aryl Halides with Aryl Boronic Acids Catalyzed by Phosphine-Free NiCl2·6H2O
10.1016/s0040-4039(02)00716-5 · 2002 · External reference
“Naked Nickel”-Catalyzed Heteroaryl–Heteroaryl Suzuki–Miyaura Coupling
10.1002/anie.202424051 · 2025 · External reference
Advancing Base-Metal Catalysis: Developing Nickel Catalysis for the Direct Telescope of Miyaura Borylation and Suzuki–Miyaura Cross-Coupling Reactions
10.1021/acs.oprd.4c00327 · 2024 · External reference
Activator-Promoted Aryl Halide-Dependent Chemoselective Buchwald–Hartwig and Suzuki–Miyaura Type Cross-Coupling Reactions
10.1021/acs.orglett.0c01600 · 2020 · External reference
Development of a Commercial Manufacturing Process for Sotorasib, a First-in-Class KRASG12C Inhibitor
10.1021/acs.oprd.2c00249 · 2022 · External reference
Efficient Synthesis of Chiral 1,1′-Binaphthalenes by the Asymmetric Suzuki–Miyaura Reaction: Dramatic Synthetic Improvement by Simple Purification of Naphthylboronic Acids
10.1002/chem.200600616 · 2006 · External reference
Transfer Learning-Enabled Ligand Prediction for Ni-Catalyzed Atroposelective Suzuki–Miyaura Cross-Coupling Based on Mechanistic Similarity: Leveraging Pd Knowledge for Ni Discovery
10.1021/jacs.5c00838 · 2025 · External reference
Recent Advances in Homogeneous Nickel Catalysis
10.1038/nature13274 · 2014 · External reference
Univariate Classification of Phosphine Ligation State and Reactivity in Cross-Coupling Catalysis
10.1126/science.abj4213 · 2021 · External reference
Comparison of Monophosphine and Bisphosphine Precatalysts for Ni-Catalyzed Suzuki–Miyaura Cross-Coupling: Understanding the Role of the Ligation State in Catalysis
10.1021/acscatal.3c01331 · 2023 · External reference
Highly Reactive, Single-Component Nickel Catalyst Precursor for Suzuki–Miyuara Cross-Coupling of Heteroaryl Boronic Acids with Heteroaryl Halides
10.1002/anie.201207428 · 2012 · External reference
Mechanistic Investigation of the Nickel-Catalyzed Suzuki Reaction of N,O-Acetals: Evidence for Boronic Acid Assisted Oxidative Addition and an Iminium Activation Pathway
10.1021/ja3079362 · 2012 · External reference
(DPEPhos)Ni(Mesityl)Br: An Air-Stable Pre-Catalyst for Challenging Suzuki–Miyaura Cross-Couplings Leading to Unsymmetrical Biheteroaryls
10.1055/s-0036-1591523 · 2018 · External reference
Unresolved reference
External reference
Biphenylene-Substituted Ruthenocenylphosphine for Suzuki–Miyaura Coupling of Aryl Chlorides
10.1021/ol800567q · 2008 · External reference
Tetra-Ortho-Substituted Biaryls through Palladium-Catalyzed Suzuki–Miyaura Couplings with a Diaminochlorophosphine Ligand
10.1021/ol1000186 · 2010 · External reference
A Rationally Designed Universal Catalyst for Suzuki–Miyaura Coupling Processes
10.1002/ange.200353615 · 2004 · External reference
An N-Heterocyclic Carbene Ligand with Flexible Steric Bulk Allows Suzuki Cross-Coupling of Sterically Hindered Aryl Chlorides at Room Temperature
10.1002/anie.200351325 · 2003 · External reference
Protodeboronation of (Hetero)Arylboronic Esters: Direct versus Prehydrolytic Pathways and Self-/Auto-Catalysis
10.1021/jacs.1c06863 · 2021 · External reference
Protodeboronation of Heteroaromatic, Vinyl, and Cyclopropyl Boronic Acids: pH–Rate Profiles, Autocatalysis, and Disproportionation
10.1021/jacs.6b03283 · 2016 · External reference
The Boroxine–Boronic Acid Equilibrium
10.1021/jacs.5c10835 · 2025 · External reference
Enabling Suzuki–Miyaura Coupling of Lewis-Basic Arylboronic Esters with a Nonprecious Metal Catalyst
10.1039/d2sc03877c · 2022 · External reference
Taming Nickel-Catalyzed Suzuki-Miyaura Coupling: A Mechanistic Focus on Boron-to-Nickel Transmetalation
10.1021/acscatal.8b00933 · 2018 · External reference
Development of Effective Bidentate Diphosphine Ligands of Ruthenium Catalysts toward Practical Hydrogenation of Carboxylic Acids
10.1246/bcsj.20210023 · 2021 · External reference
Bayesian Reaction Optimization as a Tool for Chemical Synthesis
10.1038/s41586-021-03213-y · 2021 · External reference
A Multi-Objective Active Learning Platform and Web App for Reaction Optimization
10.1021/jacs.2c08592 · 2022 · External reference
Development of an Air-Stable, Broadly Applicable Nickel Source for Nickel-Catalyzed Cross-Coupling
10.1021/acscatal.5b00498 · 2015 · External reference
A Modular, Air-Stable Nickel Precatalyst
10.1021/acs.orglett.5b00766 · 2015 · External reference
A Highly Active Suzuki Catalyst for the Synthesis of Sterically Hindered Biaryls: Novel Ligand Coordination
10.1021/ja017082r · 2002 · External reference
Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation
10.1021/ja4064469 · 2013 · External reference
A Robustness Screen for the Rapid Assessment of Chemical Reactions
10.1038/nchem.1669 · 2013 · External reference
Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Chlorides with Primary Alkyl Chlorides
10.1021/jacs.0c02673 · 2020 · External reference
Reaktionen von Heteroolefinen an Zentralmetallen in Niedrigen Oxidationsstufen: Stabile Aldehydkomplexe Des Nickel(O) Und Verwandte Verbindungen
10.1016/s0022-328x(00)90632-6 · 1980 · External reference
Unexpected Nickel Complex Speciation Unlocks Alternative Pathways for the Reactions of Alkyl Halides with Dppf-Nickel(0)
10.1021/acscatal.0c02514 · 2020 · External reference
Comprehensive Study of the Reactions Between Chelating Phosphines and Ni(Cod)2
10.1021/acs.organomet.8b00438 · 2018 · External reference
Unresolved reference
External reference
Synthesis, Mechanism of Formation, and Catalytic Activity of Xantphos Nickel π-Complexes
10.1039/c4cc07590k · 2014 · External reference
Fundamental Studies and Development of Nickel-Catalyzed Trifluoromethylthiolation of Aryl Chlorides: Active Catalytic Species and Key Roles of Ligand and Traceless MeCN Additive Revealed
10.1021/jacs.5b00538 · 2015 · External reference
A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes
10.1021/om500156q · 2014 · External reference
PAd2-DalPhos Enables the Nickel-Catalyzed C–N Cross-Coupling of Primary Heteroarylamines and (Hetero)Aryl Chlorides
10.1002/anie.201900095 · 2019 · External reference
Evaluating 1,1′-Bis(Phosphino)Ferrocene Ancillary Ligand Variants in the Nickel-Catalyzed C–N Cross-Coupling of (Hetero)Aryl Chlorides
10.1021/acs.organomet.6b00885 · 2017 · External reference
Structural Variation in Copper(I) Complexes with Pyridylmethylamide Ligands : Structural Analysis with a New Four-Coordinate Geometry Index, τ4
10.1039/b617136b · 2007 · External reference
[(Dcpp)Ni(η2-Arene)] Precursors: Synthesis, Reactivity, and Catalytic Application to the Suzuki–Miyaura Reaction
10.1021/acs.organomet.9b00834 · 2020 · External reference
Unresolved reference
External reference
Unresolved reference
External reference
Unresolved reference
External reference
Variable Temperature NMR Experiment Studying Restricted Bond Rotation
10.1021/acs.jchemed.0c00057 · 2020 · External reference
Elucidating the Mechanism of Excited-State Bond Homolysis in Nickel–Bipyridine Photoredox Catalysts
10.1021/jacs.2c01356 · 2022 · External reference
Chemical Exchange in NMR
10.1016/j.pnmrs.2003.08.001 · 2003 · External reference
Main Group Chemistry on a Metal Framework. Reactions of [(µ-H)Fe3(CO)9BH2R]- (R = H, CH3) with Lewis Bases
10.1021/ja00276a026 · 1986 · External reference
Trends in the Usage of Bidentate Phosphines as Ligands in Nickel Catalysis
10.1021/acs.chemrev.9b00682 · 2020 · External reference
Palladium-Catalyzed Coupling Reactions of Aryl Chlorides
10.1002/1521-3773(20021115)41:22<4176::aid-anie4176>3.0.co;2-u · ExternalCitation · doi-reference
A Rationally Designed Universal Catalyst for Suzuki–Miyaura Coupling Processes
10.1002/ange.200353615 · ExternalCitation · doi-reference
An N-Heterocyclic Carbene Ligand with Flexible Steric Bulk Allows Suzuki Cross-Coupling of Sterically Hindered Aryl Chlorides at Room Temperature
10.1002/anie.200351325 · ExternalCitation · doi-reference
Highly Reactive, Single-Component Nickel Catalyst Precursor for Suzuki–Miyuara Cross-Coupling of Heteroaryl Boronic Acids with Heteroaryl Halides
10.1002/anie.201207428 · ExternalCitation · doi-reference
PAd2-DalPhos Enables the Nickel-Catalyzed C–N Cross-Coupling of Primary Heteroarylamines and (Hetero)Aryl Chlorides
10.1002/anie.201900095 · ExternalCitation · doi-reference
“Naked Nickel”-Catalyzed Heteroaryl–Heteroaryl Suzuki–Miyaura Coupling
10.1002/anie.202424051 · ExternalCitation · doi-reference
Nickel Bromide Catalyzed Ligand-Free and Activator-less Suzuki Coupling Reactions
10.1002/cctc.202200440 · ExternalCitation · doi-reference
Efficient Synthesis of Chiral 1,1′-Binaphthalenes by the Asymmetric Suzuki–Miyaura Reaction: Dramatic Synthetic Improvement by Simple Purification of Naphthylboronic Acids
10.1002/chem.200600616 · ExternalCitation · doi-reference
Chemical Exchange in NMR
10.1016/j.pnmrs.2003.08.001 · ExternalCitation · doi-reference
Reaktionen von Heteroolefinen an Zentralmetallen in Niedrigen Oxidationsstufen: Stabile Aldehydkomplexe Des Nickel(O) Und Verwandte Verbindungen
10.1016/s0022-328x(00)90632-6 · ExternalCitation · doi-reference
Suzuki Cross-Coupling of Aryl Halides with Aryl Boronic Acids Catalyzed by Phosphine-Free NiCl2·6H2O
10.1016/s0040-4039(02)00716-5 · ExternalCitation · doi-reference
Trends in the Usage of Bidentate Phosphines as Ligands in Nickel Catalysis
10.1021/acs.chemrev.9b00682 · ExternalCitation · doi-reference
Variable Temperature NMR Experiment Studying Restricted Bond Rotation
10.1021/acs.jchemed.0c00057 · ExternalCitation · doi-reference
Analysis of Past and Present Synthetic Methodologies on Medicinal Chemistry: Where Have All the New Reactions Gone?
10.1021/acs.jmedchem.5b01409 · ExternalCitation · doi-reference
Development of a Commercial Manufacturing Process for Sotorasib, a First-in-Class KRASG12C Inhibitor
10.1021/acs.oprd.2c00249 · ExternalCitation · doi-reference
Advancing Base-Metal Catalysis: Developing Nickel Catalysis for the Direct Telescope of Miyaura Borylation and Suzuki–Miyaura Cross-Coupling Reactions
10.1021/acs.oprd.4c00327 · ExternalCitation · doi-reference
Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling Facilitated by a Weak Amine Base with Water as a Cosolvent
10.1021/acs.organomet.2c00197 · ExternalCitation · doi-reference
Evaluating 1,1′-Bis(Phosphino)Ferrocene Ancillary Ligand Variants in the Nickel-Catalyzed C–N Cross-Coupling of (Hetero)Aryl Chlorides
10.1021/acs.organomet.6b00885 · ExternalCitation · doi-reference
Comprehensive Study of the Reactions Between Chelating Phosphines and Ni(Cod)2
10.1021/acs.organomet.8b00438 · ExternalCitation · doi-reference
[(Dcpp)Ni(η2-Arene)] Precursors: Synthesis, Reactivity, and Catalytic Application to the Suzuki–Miyaura Reaction
10.1021/acs.organomet.9b00834 · ExternalCitation · doi-reference
Activator-Promoted Aryl Halide-Dependent Chemoselective Buchwald–Hartwig and Suzuki–Miyaura Type Cross-Coupling Reactions
10.1021/acs.orglett.0c01600 · ExternalCitation · doi-reference
A Modular, Air-Stable Nickel Precatalyst
10.1021/acs.orglett.5b00766 · ExternalCitation · doi-reference
Unexpected Nickel Complex Speciation Unlocks Alternative Pathways for the Reactions of Alkyl Halides with Dppf-Nickel(0)
10.1021/acscatal.0c02514 · ExternalCitation · doi-reference
Comparison of Monophosphine and Bisphosphine Precatalysts for Ni-Catalyzed Suzuki–Miyaura Cross-Coupling: Understanding the Role of the Ligation State in Catalysis
10.1021/acscatal.3c01331 · ExternalCitation · doi-reference
Development of an Air-Stable, Broadly Applicable Nickel Source for Nickel-Catalyzed Cross-Coupling
10.1021/acscatal.5b00498 · ExternalCitation · doi-reference
Process-Ready Nickel-Catalyzed Suzuki–Miyaura Coupling Enabled by tri-ProPhos
10.1021/acscatal.5c07157 · ExternalCitation · doi-reference
Taming Nickel-Catalyzed Suzuki-Miyaura Coupling: A Mechanistic Focus on Boron-to-Nickel Transmetalation
10.1021/acscatal.8b00933 · ExternalCitation · doi-reference
Palladium-Catalyzed Suzuki–Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands
10.1021/ar800036s · ExternalCitation · doi-reference
Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals
10.1021/cr100346g · ExternalCitation · doi-reference
Main Group Chemistry on a Metal Framework. Reactions of [(µ-H)Fe3(CO)9BH2R]- (R = H, CH3) with Lewis Bases
10.1021/ja00276a026 · ExternalCitation · doi-reference
A Highly Active Suzuki Catalyst for the Synthesis of Sterically Hindered Biaryls: Novel Ligand Coordination
10.1021/ja017082r · ExternalCitation · doi-reference
Mechanistic Investigation of the Nickel-Catalyzed Suzuki Reaction of N,O-Acetals: Evidence for Boronic Acid Assisted Oxidative Addition and an Iminium Activation Pathway
10.1021/ja3079362 · ExternalCitation · doi-reference
Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation
10.1021/ja4064469 · ExternalCitation · doi-reference
Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Chlorides with Primary Alkyl Chlorides
10.1021/jacs.0c02673 · ExternalCitation · doi-reference
Protodeboronation of (Hetero)Arylboronic Esters: Direct versus Prehydrolytic Pathways and Self-/Auto-Catalysis
10.1021/jacs.1c06863 · ExternalCitation · doi-reference
Elucidating the Mechanism of Excited-State Bond Homolysis in Nickel–Bipyridine Photoredox Catalysts
10.1021/jacs.2c01356 · ExternalCitation · doi-reference
A Multi-Objective Active Learning Platform and Web App for Reaction Optimization
10.1021/jacs.2c08592 · ExternalCitation · doi-reference
ProPhos: A Ligand for Promoting Nickel-Catalyzed Suzuki-Miyaura Coupling Inspired by Mechanistic Insights into Transmetalation
10.1021/jacs.4c00370 · ExternalCitation · doi-reference
Fundamental Studies and Development of Nickel-Catalyzed Trifluoromethylthiolation of Aryl Chlorides: Active Catalytic Species and Key Roles of Ligand and Traceless MeCN Additive Revealed
10.1021/jacs.5b00538 · ExternalCitation · doi-reference
Transfer Learning-Enabled Ligand Prediction for Ni-Catalyzed Atroposelective Suzuki–Miyaura Cross-Coupling Based on Mechanistic Similarity: Leveraging Pd Knowledge for Ni Discovery
10.1021/jacs.5c00838 · ExternalCitation · doi-reference
The Boroxine–Boronic Acid Equilibrium
10.1021/jacs.5c10835 · ExternalCitation · doi-reference
Protodeboronation of Heteroaromatic, Vinyl, and Cyclopropyl Boronic Acids: pH–Rate Profiles, Autocatalysis, and Disproportionation
10.1021/jacs.6b03283 · ExternalCitation · doi-reference
Tetra-Ortho-Substituted Biaryls through Palladium-Catalyzed Suzuki–Miyaura Couplings with a Diaminochlorophosphine Ligand
10.1021/ol1000186 · ExternalCitation · doi-reference
Biphenylene-Substituted Ruthenocenylphosphine for Suzuki–Miyaura Coupling of Aryl Chlorides
10.1021/ol800567q · ExternalCitation · doi-reference
A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes
10.1021/om500156q · ExternalCitation · doi-reference
Recent Advances in Homogeneous Nickel Catalysis
10.1038/nature13274 · ExternalCitation · doi-reference
A Robustness Screen for the Rapid Assessment of Chemical Reactions
10.1038/nchem.1669 · ExternalCitation · doi-reference
Bayesian Reaction Optimization as a Tool for Chemical Synthesis
10.1038/s41586-021-03213-y · ExternalCitation · doi-reference
Structural Variation in Copper(I) Complexes with Pyridylmethylamide Ligands : Structural Analysis with a New Four-Coordinate Geometry Index, τ4
10.1039/b617136b · ExternalCitation · doi-reference
Synthesis, Mechanism of Formation, and Catalytic Activity of Xantphos Nickel π-Complexes
10.1039/c4cc07590k · ExternalCitation · doi-reference
Enabling Suzuki–Miyaura Coupling of Lewis-Basic Arylboronic Esters with a Nonprecious Metal Catalyst
10.1039/d2sc03877c · ExternalCitation · doi-reference
(DPEPhos)Ni(Mesityl)Br: An Air-Stable Pre-Catalyst for Challenging Suzuki–Miyaura Cross-Couplings Leading to Unsymmetrical Biheteroaryls
10.1055/s-0036-1591523 · ExternalCitation · doi-reference
Univariate Classification of Phosphine Ligation State and Reactivity in Cross-Coupling Catalysis
10.1126/science.abj4213 · ExternalCitation · doi-reference
Development of Effective Bidentate Diphosphine Ligands of Ruthenium Catalysts toward Practical Hydrogenation of Carboxylic Acids
10.1246/bcsj.20210023 · ExternalCitation · doi-reference
