Research graph
References from Outer-Sphere Hydrogen Bonds Amplify Mutual Actinide Separation. Local targets link to admitted publications; unresolved targets remain external evidence.
Six degrees of actinide separation
10.1038/s41570-024-00610-5 · 2024 · External reference
Production of Cf-252 and other transplutonium isotopes at Oak Ridge National Laboratory
10.1515/ract-2020-0008 · 2020 · External reference
Californium gleaming
10.1038/nchem.2035 · 2014 · External reference
Isolation and characterization of a californium metallocene
10.1038/s41586-021-04027-8 · 2021 · External reference
Emergence of californium as the second transitional element in the actinide series
10.1038/ncomms7827 · 2015 · External reference
Higher Oxidation States of Americium: Preparation, Characterization and Use for Separations
10.1021/cr100181f · 2011 · External reference
Solvent extraction systems for mutual separation of Am(III) and Cm(III) from nitric acid solutions. A review of recent state-of-the-art
10.1080/07366299.2020.1856998 · 2021 · External reference
Micronuclear battery based on a coalescent energy transducer
10.1038/s41586-024-07933-9 · 2024 · External reference
Curium(iii) luminescence spectroscopy as a tool for species determination
10.1039/d5cs00764j · 2025 · External reference
10.2172/1782041
10.2172/1782041 · 2021 · External reference
10.2172/1606847
10.2172/1606847 · 2019 · External reference
Californium
10.1007/1-4020-3598-5_11 · 2006 · External reference
Californium Isotopes Proposed for Intracavity and Interstitial Radiation Therapy with Neutrons
10.1038/2061058a0 · 1965 · External reference
The complexation and solvent extraction properties of a phenanthroline diamide extractant for trivalent actinide and lanthanide ions
10.1039/d5qi01056j · 2025 · External reference
Experimental and theoretical studies on the extraction behavior of Cf(iii) by NTAamide(C8) ligand and the separation of Cf(iii)/Cm(iii)
10.1039/d2ra07660h · 2023 · External reference
Spontaneous Partitioning of Californium from Curium: Curious Cases from the Crystallization of Curium Coordination Complexes
10.1021/acs.inorgchem.5b02052 · 2015 · External reference
Separation of californium from curium and berkelium from cerium by extraction chromatography
10.1021/ac60251a012 · 1967 · External reference
Demonstration of the LUCA process for the separation of americium(III) from curium(III), californium(III), and lanthanides(III) in acidic solution using a synergistic mixture of bis(chlorophenyl)dithiophosphinic acid and tris(2-ethylhexyl)phosphate
10.1524/ract.2010.1708 · 2010 · External reference
Ultrafiltration separation of Am(VI)-polyoxometalate from lanthanides
10.1038/s41586-023-05840-z · 2023 · External reference
Ultra-Efficient Americium/Lanthanide Separation through Oxidation State Control
10.1021/jacs.2c00594 · 2022 · External reference
Separation of Americium from Curium through Oxidation State Control with Record Efficiency
10.1021/acs.analchem.2c01492 · 2022 · External reference
Transuranium organometallic chemistry
10.1038/s41570-025-00732-4 · 2025 · External reference
Separation of 248Cm from a 252Cf neutron source for production of Cm targets
10.1524/ract.2001.89.9.543 · 2001 · External reference
Hydrophilic chelators for the coordination and separation of radioactive f-block elements
10.1360/nso/20240028 · 2024 · External reference
Solvent extraction: the coordination chemistry behind extractive metallurgy
10.1039/c3cs60275c · 2014 · External reference
Separation of Actinides(III) from Lanthanides(III) in Simulated Nuclear Waste Streams using 6,6′-Bis-(5,6-dipentyl-[1,2,4]triazin-3-yl)-[2,2′]bipyridinyl (C5-BTBP) in Cyclohexanone
10.1080/07366290600952659 · 2006 · External reference
Effect of f-electron configurations on the adsorption of trivalent f-elements on tertiary pyridine resin in hydrochloric acid/alcohol mixed solvents
10.1016/j.jallcom.2003.11.111 · 2004 · External reference
Solvent extraction of uranium, neptunium, plutonium, americium, curium and californium ions by bis(1-phenyl-3-methyl-4-acylpyrazol-5-one) derivatives
10.1016/s0003-2670(00)01324-6 · 2001 · External reference
Extraction Studies of Selected Actinide Ions from Aqueous Solutions Wtth 4.Benzoyl-24-Dihydro-5-Methyl-2-Phenyl-3h-Pyrazol-3-Thione and Tri-N-Octylphosphtne Oxide
10.1080/07366299208918113 · 1992 · External reference
Extraction of Transplutonium Elements by Di-2-Ethylhexylphosphoric Acid
10.1524/ract.1970.14.1.27 · 1970 · External reference
10.2172/1394273
10.2172/1394273 · 2017 · External reference
Organophosphorus Extractants: A Critical Choice for Actinides/Lanthanides Separation in Nuclear Fuel Cycle
10.1002/chem.202300456 · 2023 · External reference
A first phosphine oxide-based extractant with high Am/Cm selectivity
10.1039/c8dt04729d · 2019 · External reference
Water Soluble PDCA Derivatives for Selective Ln(III)/An(III) and Am(III)/Cm(III) Separation
10.1080/07366299.2014.974449 · 2015 · External reference
Effective separation of the actinides Am(iii) and Cm(iii) by electronic modulation of bis-(1,2,4-triazin-3-yl)phenanthrolines
10.1039/c5cc00567a · 2015 · External reference
6,6′-Bis(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-benzo[1,2,4]triazin-3-yl) [2,2′]bipyridine, an Effective Extracting Agent for the Separation of Americium(III) and Curium(III) from the Lanthanides
10.1080/07366290600761936 · 2006 · External reference
A Simple yet Efficient Hydrophilic Phenanthroline-Based Ligand for Selective Am(III) Separation under High Acidity
10.1021/acscentsci.3c00504 · 2023 · External reference
Similar but Different: Structural and Spectroscopic Characterization of Series of Neodymium, Europium, Americium, and Curium Coordination Complexes
10.1021/jacs.5c00861 · 2025 · External reference
Synthesis and Characterization of Tris-chelate Complexes for Understanding f-Orbital Bonding in Later Actinides
10.1021/jacs.8b10251 · 2019 · External reference
On the Design of Effective Water-Soluble Actinide-Masking Ligands Through Ligand Structure Modulation
10.1002/advs.202512292 · 2025 · External reference
Size Selective Ligand Tug of War Strategy to Separate Rare Earth Elements
10.1021/jacsau.2c00671 · 2023 · External reference
Solid-phase-based separation of transuranium elements: Current status and insights into the synergistic separation mechanism
10.1016/j.ccr.2025.217472 · 2026 · External reference
Separation and complexation of f-block elements using hard-soft donors combined phenanthroline extractants
10.1016/j.ccr.2023.215404 · 2023 · External reference
Sulfur donating extractants for the separation of trivalent actinides and lanthanides
10.1016/j.ccr.2020.213446 · 2020 · External reference
Conformationally Adaptable Extractant Flexes Strong Lanthanide Reverse-Size Selectivity
10.1021/jacs.4c15074 · 2025 · External reference
A sustainable cobalt separation with validation by techno-economic analysis and life-cycle assessment
10.1016/j.chempr.2024.10.028 · 2025 · External reference
Using second-sphere recognition for selective metal separation by precipitation
10.1016/j.chempr.2025.102581 · 2025 · External reference
Metadynamics investigation of lanthanide solvation free energy landscapes and insights into separations energetics
10.1039/d4sc05061d · 2024 · External reference
Trefoil-Shaped Outer-Sphere Ion Clusters Mediate Lanthanide(III) Ion Transport with Diglycolamide Ligands
10.1021/jacs.7b07318 · 2017 · External reference
Nitrate and water in the first coordination shells of lanthanide complexes
10.1016/j.inoche.2025.114844 · 2025 · External reference
Changes in nitrate binding with lanthanides in BLPhen complexes
10.1016/j.molliq.2023.122573 · 2023 · External reference
Performance and Mechanism for the Selective Separation of Trivalent Americium from Lanthanides by a Tetradentate Phenanthroline Ligand in Ionic Liquid
10.1021/acs.inorgchem.9b03566 · 2020 · External reference
Trivalent Actinide and Lanthanide Separations by Tetradentate Nitrogen Ligands: A Quantum Chemistry Study
10.1021/ic200078j · 2011 · External reference
Development of a Selective Americium Separation Process Using H4TPAEN as Water-Soluble Stripping Agent
10.1080/07366299.2019.1643569 · 2019 · External reference
Combination of DGA and LN Columns: A Versatile Option for Isotope Production and Purification at Oak Ridge National Laboratory
10.1080/07366299.2020.1831244 · 2021 · External reference
Separation of transplutonium and rare-earth elements by extraction with HDEHP from DTPA solutions
10.1007/bf02519439 · 1978 · External reference
Preferential extraction of lanthanides over trivalent actinides by monoacidic organophosphates from carboxylic acids and from mixtures of carboxylic and aminopolyacetic acids
10.1016/0022-1902(68)80089-2 · 1968 · External reference
On the design of n-octanol soluble Am(III)/Eu(III) separation ligands
10.1016/j.seppur.2025.132788 · 2025 · External reference
Amino Acid Decorated Phenanthroline Diimide as Sustainable Hydrophilic Am(III) Masking Agent with High Acid Resistance
10.1021/jacsau.4c00659 · 2024 · External reference
On the Design of Effective Water-Soluble Actinide-Masking Ligands Through Ligand Structure Modulation
10.1002/advs.202512292 · ExternalCitation · doi-reference
Organophosphorus Extractants: A Critical Choice for Actinides/Lanthanides Separation in Nuclear Fuel Cycle
10.1002/chem.202300456 · ExternalCitation · doi-reference
Californium
10.1007/1-4020-3598-5_11 · ExternalCitation · doi-reference
Separation of transplutonium and rare-earth elements by extraction with HDEHP from DTPA solutions
10.1007/bf02519439 · ExternalCitation · doi-reference
Preferential extraction of lanthanides over trivalent actinides by monoacidic organophosphates from carboxylic acids and from mixtures of carboxylic and aminopolyacetic acids
10.1016/0022-1902(68)80089-2 · ExternalCitation · doi-reference
Sulfur donating extractants for the separation of trivalent actinides and lanthanides
10.1016/j.ccr.2020.213446 · ExternalCitation · doi-reference
Separation and complexation of f-block elements using hard-soft donors combined phenanthroline extractants
10.1016/j.ccr.2023.215404 · ExternalCitation · doi-reference
Solid-phase-based separation of transuranium elements: Current status and insights into the synergistic separation mechanism
10.1016/j.ccr.2025.217472 · ExternalCitation · doi-reference
A sustainable cobalt separation with validation by techno-economic analysis and life-cycle assessment
10.1016/j.chempr.2024.10.028 · ExternalCitation · doi-reference
Using second-sphere recognition for selective metal separation by precipitation
10.1016/j.chempr.2025.102581 · ExternalCitation · doi-reference
Nitrate and water in the first coordination shells of lanthanide complexes
10.1016/j.inoche.2025.114844 · ExternalCitation · doi-reference
Effect of f-electron configurations on the adsorption of trivalent f-elements on tertiary pyridine resin in hydrochloric acid/alcohol mixed solvents
10.1016/j.jallcom.2003.11.111 · ExternalCitation · doi-reference
Changes in nitrate binding with lanthanides in BLPhen complexes
10.1016/j.molliq.2023.122573 · ExternalCitation · doi-reference
On the design of n-octanol soluble Am(III)/Eu(III) separation ligands
10.1016/j.seppur.2025.132788 · ExternalCitation · doi-reference
Solvent extraction of uranium, neptunium, plutonium, americium, curium and californium ions by bis(1-phenyl-3-methyl-4-acylpyrazol-5-one) derivatives
10.1016/s0003-2670(00)01324-6 · ExternalCitation · doi-reference
Separation of californium from curium and berkelium from cerium by extraction chromatography
10.1021/ac60251a012 · ExternalCitation · doi-reference
Separation of Americium from Curium through Oxidation State Control with Record Efficiency
10.1021/acs.analchem.2c01492 · ExternalCitation · doi-reference
Spontaneous Partitioning of Californium from Curium: Curious Cases from the Crystallization of Curium Coordination Complexes
10.1021/acs.inorgchem.5b02052 · ExternalCitation · doi-reference
Performance and Mechanism for the Selective Separation of Trivalent Americium from Lanthanides by a Tetradentate Phenanthroline Ligand in Ionic Liquid
10.1021/acs.inorgchem.9b03566 · ExternalCitation · doi-reference
A Simple yet Efficient Hydrophilic Phenanthroline-Based Ligand for Selective Am(III) Separation under High Acidity
10.1021/acscentsci.3c00504 · ExternalCitation · doi-reference
Higher Oxidation States of Americium: Preparation, Characterization and Use for Separations
10.1021/cr100181f · ExternalCitation · doi-reference
Trivalent Actinide and Lanthanide Separations by Tetradentate Nitrogen Ligands: A Quantum Chemistry Study
10.1021/ic200078j · ExternalCitation · doi-reference
Ultra-Efficient Americium/Lanthanide Separation through Oxidation State Control
10.1021/jacs.2c00594 · ExternalCitation · doi-reference
Conformationally Adaptable Extractant Flexes Strong Lanthanide Reverse-Size Selectivity
10.1021/jacs.4c15074 · ExternalCitation · doi-reference
Similar but Different: Structural and Spectroscopic Characterization of Series of Neodymium, Europium, Americium, and Curium Coordination Complexes
10.1021/jacs.5c00861 · ExternalCitation · doi-reference
Trefoil-Shaped Outer-Sphere Ion Clusters Mediate Lanthanide(III) Ion Transport with Diglycolamide Ligands
10.1021/jacs.7b07318 · ExternalCitation · doi-reference
Synthesis and Characterization of Tris-chelate Complexes for Understanding f-Orbital Bonding in Later Actinides
10.1021/jacs.8b10251 · ExternalCitation · doi-reference
Size Selective Ligand Tug of War Strategy to Separate Rare Earth Elements
10.1021/jacsau.2c00671 · ExternalCitation · doi-reference
Amino Acid Decorated Phenanthroline Diimide as Sustainable Hydrophilic Am(III) Masking Agent with High Acid Resistance
10.1021/jacsau.4c00659 · ExternalCitation · doi-reference
Californium Isotopes Proposed for Intracavity and Interstitial Radiation Therapy with Neutrons
10.1038/2061058a0 · ExternalCitation · doi-reference
Californium gleaming
10.1038/nchem.2035 · ExternalCitation · doi-reference
Emergence of californium as the second transitional element in the actinide series
10.1038/ncomms7827 · ExternalCitation · doi-reference
Six degrees of actinide separation
10.1038/s41570-024-00610-5 · ExternalCitation · doi-reference
Transuranium organometallic chemistry
10.1038/s41570-025-00732-4 · ExternalCitation · doi-reference
Isolation and characterization of a californium metallocene
10.1038/s41586-021-04027-8 · ExternalCitation · doi-reference
Ultrafiltration separation of Am(VI)-polyoxometalate from lanthanides
10.1038/s41586-023-05840-z · ExternalCitation · doi-reference
Micronuclear battery based on a coalescent energy transducer
10.1038/s41586-024-07933-9 · ExternalCitation · doi-reference
Solvent extraction: the coordination chemistry behind extractive metallurgy
10.1039/c3cs60275c · ExternalCitation · doi-reference
Effective separation of the actinides Am(iii) and Cm(iii) by electronic modulation of bis-(1,2,4-triazin-3-yl)phenanthrolines
10.1039/c5cc00567a · ExternalCitation · doi-reference
A first phosphine oxide-based extractant with high Am/Cm selectivity
10.1039/c8dt04729d · ExternalCitation · doi-reference
Experimental and theoretical studies on the extraction behavior of Cf(iii) by NTAamide(C8) ligand and the separation of Cf(iii)/Cm(iii)
10.1039/d2ra07660h · ExternalCitation · doi-reference
Metadynamics investigation of lanthanide solvation free energy landscapes and insights into separations energetics
10.1039/d4sc05061d · ExternalCitation · doi-reference
Curium(iii) luminescence spectroscopy as a tool for species determination
10.1039/d5cs00764j · ExternalCitation · doi-reference
The complexation and solvent extraction properties of a phenanthroline diamide extractant for trivalent actinide and lanthanide ions
10.1039/d5qi01056j · ExternalCitation · doi-reference
6,6′-Bis(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-benzo[1,2,4]triazin-3-yl) [2,2′]bipyridine, an Effective Extracting Agent for the Separation of Americium(III) and Curium(III) from the Lanthanides
10.1080/07366290600761936 · ExternalCitation · doi-reference
Separation of Actinides(III) from Lanthanides(III) in Simulated Nuclear Waste Streams using 6,6′-Bis-(5,6-dipentyl-[1,2,4]triazin-3-yl)-[2,2′]bipyridinyl (C5-BTBP) in Cyclohexanone
10.1080/07366290600952659 · ExternalCitation · doi-reference
Water Soluble PDCA Derivatives for Selective Ln(III)/An(III) and Am(III)/Cm(III) Separation
10.1080/07366299.2014.974449 · ExternalCitation · doi-reference
Development of a Selective Americium Separation Process Using H4TPAEN as Water-Soluble Stripping Agent
10.1080/07366299.2019.1643569 · ExternalCitation · doi-reference
Combination of DGA and LN Columns: A Versatile Option for Isotope Production and Purification at Oak Ridge National Laboratory
10.1080/07366299.2020.1831244 · ExternalCitation · doi-reference
Solvent extraction systems for mutual separation of Am(III) and Cm(III) from nitric acid solutions. A review of recent state-of-the-art
10.1080/07366299.2020.1856998 · ExternalCitation · doi-reference
Extraction Studies of Selected Actinide Ions from Aqueous Solutions Wtth 4.Benzoyl-24-Dihydro-5-Methyl-2-Phenyl-3h-Pyrazol-3-Thione and Tri-N-Octylphosphtne Oxide
10.1080/07366299208918113 · ExternalCitation · doi-reference
Hydrophilic chelators for the coordination and separation of radioactive f-block elements
10.1360/nso/20240028 · ExternalCitation · doi-reference
Production of Cf-252 and other transplutonium isotopes at Oak Ridge National Laboratory
10.1515/ract-2020-0008 · ExternalCitation · doi-reference
Extraction of Transplutonium Elements by Di-2-Ethylhexylphosphoric Acid
10.1524/ract.1970.14.1.27 · ExternalCitation · doi-reference
Separation of 248Cm from a 252Cf neutron source for production of Cm targets
10.1524/ract.2001.89.9.543 · ExternalCitation · doi-reference
Demonstration of the LUCA process for the separation of americium(III) from curium(III), californium(III), and lanthanides(III) in acidic solution using a synergistic mixture of bis(chlorophenyl)dithiophosphinic acid and tris(2-ethylhexyl)phosphate
10.1524/ract.2010.1708 · ExternalCitation · doi-reference
10.2172/1394273
10.2172/1394273 · ExternalCitation · doi-reference
10.2172/1606847
10.2172/1606847 · ExternalCitation · doi-reference
10.2172/1782041
10.2172/1782041 · ExternalCitation · doi-reference
