References

Construction of Carbocycles from Methylenecyclopropanes

10.1002/adsc.201900615 · ExternalCitation · doi-reference

Cobalt-Catalyzed Intramolecular Cycloadditions of Alkenylidenecyclopropanes with Alkenes and Dienes

10.1002/adsc.202301040 · ExternalCitation · doi-reference

Diastereoselective Rhodium-Catalyzed [(3+2+2)] Carbocyclization Reactions with Tethered Alkynylidenecyclopropanes: Synthesis of the Tremulane Sesquiterpene Natural Products

10.1002/ajoc.202000482 · ExternalCitation · doi-reference

Dual Catalysis: A Combined Enantioselective Brønsted Acid and Metal-Catalyzed Reaction─Metal Catalysis with Chiral Counterions

10.1002/anie.200702439 · ExternalCitation · doi-reference

Catalytic Enantioselective 1,3-Dipolar Cycloaddition Reactions of Azomethine Ylides and Alkenes by Using Phosphoramidite–Silver(I) Complexes

10.1002/anie.200801690 · ExternalCitation · doi-reference

Phosphoramidites: Privileged Ligands in Asymmetric Catalysis

10.1002/anie.200904948 · ExternalCitation · doi-reference

Asymmetric Counteranion-Directed Transition-Metal Catalysis: Enantioselective Epoxidation of Alkenes with Manganese(III) Salen Phosphate Complexes

10.1002/anie.200905332 · ExternalCitation · doi-reference

Nickel-Catalyzed [3+2+2] Cycloadditions between Alkynylidenecyclopropanes and Activated Alkenes

10.1002/anie.201004438 · ExternalCitation · doi-reference

Asymmetric Counteranion-Directed Catalysis: Concept, Definition, and Applications

10.1002/anie.201205343 · ExternalCitation · doi-reference

The Isolation and Characterization of a Rhodacycle Intermediate Implicated in Metal-Catalyzed Reactions of Alkylidenecyclopropanes

10.1002/anie.201310232 · ExternalCitation · doi-reference

Rhodium-Catalyzed[(3+2)+2] Carbocyclization of Alkynylidenecyclopropanes with Substituted Allenes: Stereoselective Construction of Tri- and Tetrasubstituted Exocyclic Olefins

10.1002/anie.201410857 · ExternalCitation · doi-reference

Rhodium-Catalyzed [3+2+2] and [2+2+2] Cycloadditions of Two Alkynes with Cyclopropylideneacetamides

10.1002/anie.201502505 · ExternalCitation · doi-reference

Highly Enantioselective Cobalt-Catalyzed (3+2) Cycloadditions of Alkynylidenecyclopropanes

10.1002/anie.202015202 · ExternalCitation · doi-reference

Transition-Metal-Catalyzed Cycloadditions for the Synthesis of Eight-Membered Carbocycles

10.1002/asia.200900712 · ExternalCitation · doi-reference

Asymmetric Induction by Chiral Borate Anions in Enantioselective Hydrogenation using a Racemic Rh–Binap Catalyst

10.1002/cctc.200900229 · ExternalCitation · doi-reference

Stereoselective Reactions Promoted by Alkali Metal Salts of Phosphoric Acid Organocatalysts

10.1002/cctc.202400328 · ExternalCitation · doi-reference

Palladium-Catalyzed [3+2] Cycloadditions of Alkylidenecyclopropanes to Imines: A Direct Approach to Pyrrolidine Scaffolds

10.1002/ceur.202500005 · ExternalCitation · doi-reference

Enantioselective Ir(I)-Catalyzed Carbocyclization of 1,6-Enynes by the Chiral Counterion Strategy

10.1002/chem.201102723 · ExternalCitation · doi-reference

Rhodium-Catalyzed Intramolecular [3+2+2] Cycloadditions between Alkylidenecyclopropanes, Alkynes, and Alkenes

10.1002/chem.201402473 · ExternalCitation · doi-reference

Chiral Phosphate in Rhodium-Catalyzed Asymmetric [2+2+2] Cycloaddition: Ligand, Counterion, or Both?

10.1002/chem.201601188 · ExternalCitation · doi-reference

Transition-Metal-Catalyzed Cycloaddition Reactions to Access Seven-Membered Rings

10.1002/chem.202002713 · ExternalCitation · doi-reference

Co-Catalyzed Asymmetric Intramolecular [3+2] Cycloaddition of Yne-Alkylidenecyclopropanes and its Reaction Mechanism

10.1002/chem.202100426 · ExternalCitation · doi-reference

Transition-Metal-Catalyzed [3+2+2] Cycloaddition Reactions

10.1002/ejoc.201701116 · ExternalCitation · doi-reference

Palladium-Catalyzed [3+2+2] Cycloaddition Between Carbonyl-Tethered Alkylidenecyclopropanes and Isocyanates

10.1002/hlca.202500011 · ExternalCitation · doi-reference

10.1016/b978-0-323-96025-0.00145-9

10.1016/b978-0-323-96025-0.00145-9 · ExternalCitation · doi-reference

Stereoselective Rhodium-Catalyzed [(3+2)+2] Carbocyclization Reaction of Trialkoxysilyl-Substituted Alkenylidenecyclopropanes with Monosubstituted Alkynes

10.1016/j.tet.2013.05.096 · ExternalCitation · doi-reference

Synthesis of a Chiral N-Heterocyclic Carbene Bearing a m-Terphenyl-Based Phosphate Moiety as an Anionic N-Substituent and its Application to Copper-Catalyzed Enantioselective Boron Conjugate Additions

10.1016/j.tetasy.2013.05.013 · ExternalCitation · doi-reference

Synthesis and Structures of a Chiral Phosphine–Phosphoric Acid Ligand and its Rhodium(I) Complexes

10.1016/j.tetasy.2015.09.016 · ExternalCitation · doi-reference

Nickel-Catalyzed [3+2+2] Cycloaddition of Ethyl Cyclopropylideneacetate and Diynes. Synthesis of 7,6- and 7,5-Fused Bicyclic Compounds

10.1016/j.tetlet.2007.03.051 · ExternalCitation · doi-reference

Catalytic Enantioselective Ring-Opening Reactions of Cyclopropanes

10.1021/acs.chemrev.0c00109 · ExternalCitation · doi-reference

Further Developments and Applications of Oxazoline-Containing Ligands in Asymmetric Catalysis

10.1021/acs.chemrev.0c00844 · ExternalCitation · doi-reference

P-Stereogenic Phosphorus Ligands in Asymmetric Catalysis

10.1021/acs.chemrev.3c00875 · ExternalCitation · doi-reference

Design Approaches That Utilize Ionic Interactions to Control Selectivity in Transition Metal Catalysis

10.1021/acs.chemrev.4c00849 · ExternalCitation · doi-reference

Controlling Stereoselectivity with Noncovalent Interactions in Chiral Phosphoric Acid Organocatalysis

10.1021/acs.chemrev.4c00869 · ExternalCitation · doi-reference

Catalytic C–C Bond Activations via Oxidative Addition to Transition Metals

10.1021/acs.chemrev.5b00138 · ExternalCitation · doi-reference

Selective Noncovalent Catalysis with Small Molecules

10.1021/acs.chemrev.5c00121 · ExternalCitation · doi-reference

Recent Methodologies That Exploit C–C Single-Bond Cleavage of Strained Ring Systems by Transition Metal Complexes

10.1021/acs.chemrev.6b00599 · ExternalCitation · doi-reference

Enantioselective Silver-Catalyzed Transformations

10.1021/acs.chemrev.6b00639 · ExternalCitation · doi-reference

Structural and Chemical Biology of Terpenoid Cyclases

10.1021/acs.chemrev.7b00287 · ExternalCitation · doi-reference

A Collection of Dispersion Induction DI, Electrostatic ES, and Hydrogen Bonding α1 and β1 Parameters for 380 Solvents and What They Say on Solvent Effects on Rates, Equilibria, and Spectra

10.1021/acs.joc.4c00858 · ExternalCitation · doi-reference

SambVca 2. A Web Tool for Analyzing Catalytic Pockets with Topographic Steric Maps

10.1021/acs.organomet.6b00371 · ExternalCitation · doi-reference

Cobalt(I)-Catalyzed (3+2+2) Cycloaddition between Alkylidenecyclopropanes, Alkynes, and Alkenes

10.1021/acs.orglett.3c03511 · ExternalCitation · doi-reference

Double-Stereodifferentiation in Rhodium-Catalyzed [2+2+2] Cycloaddition: Chiral Ligand/Chiral Counterion Matched Pair

10.1021/acs.orglett.5b01738 · ExternalCitation · doi-reference

Selection of Low-Dimensional 3-D Geometric Descriptors for Accurate Enantioselectivity Prediction

10.1021/acscatal.2c00976 · ExternalCitation · doi-reference

Carbonylative Construction and Transformation of Strained Carbocycles

10.1021/acscatal.5c08450 · ExternalCitation · doi-reference

“Cut and Sew” Transformations via Transition-Metal-Catalyzed Carbon–Carbon Bond Activation

10.1021/acscatal.6b03210 · ExternalCitation · doi-reference

Enantioselective Palladium-Catalyzed [3C+2C] and [4C+3C] Intramolecular Cycloadditions of Alkylidenecyclopropanes

10.1021/acscatal.8b01296 · ExternalCitation · doi-reference

Structural Biology and Chemistry of the Terpenoid Cyclases

10.1021/cr050286w · ExternalCitation · doi-reference

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

10.1021/cr5001496 · ExternalCitation · doi-reference

Enantioselective Reductive Coupling of 1,3-Enynes to Heterocyclic Aromatic Aldehydes and Ketones via Rhodium-Catalyzed Asymmetric Hydrogenation: Mechanistic Insight into the Role of Brønsted Acid Additives

10.1021/ja0673027 · ExternalCitation · doi-reference

Chiral Counteranions in Asymmetric Transition-Metal Catalysis: Highly Enantioselective Pd/Brønsted Acid-Catalyzed Direct α-Allylation of Aldehydes

10.1021/ja074678r · ExternalCitation · doi-reference

Palladium-Catalyzed [4+3] Intramolecular Cycloaddition of Alkylidenecyclopropanes and Dienes

10.1021/ja0756467 · ExternalCitation · doi-reference

Stereoselective Rhodium-Catalyzed [3+2+1] Carbocyclization of Alkenylidenecyclopropanes with Carbon Monoxide: Theoretical Evidence for a Trimethylenemethane Metallacycle Intermediate

10.1021/ja305467x · ExternalCitation · doi-reference

Chiral-Anion-Dependent Inversion of Diastereo- and Enantioselectivity in Carbonyl Crotylation via Ruthenium-Catalyzed Butadiene Hydrohydroxyalkylation

10.1021/ja311208a · ExternalCitation · doi-reference

Control of Diastereoselectivity for Iridium-Catalyzed Allylation of a Prochiral Nucleophile with a Phosphate Counterion

10.1021/ja311363a · ExternalCitation · doi-reference

Exploiting the Modularity of Ion-Paired Chiral Ligands for Palladium-Catalyzed Enantioselective Allylation of Benzofuran-2(3H)-ones

10.1021/ja312125a · ExternalCitation · doi-reference

Intermolecular Rhodium-Catalyzed [3+2+2] Carbocyclization of Alkenylidenecyclopropanes with Activated Alkynes: Regio- and Diastereoselective Construction of cis-Fused Bicycloheptadienes

10.1021/ja803691p · ExternalCitation · doi-reference

H-Bonded Counterion-Directed Enantioselective Au(I) Catalysis

10.1021/jacs.1c11978 · ExternalCitation · doi-reference

Intramolecular Rhodium-Catalyzed [(3+2+2)] Carbocyclization Reactions with Dienylidenecyclopropanes: A Concise and Stereoselective Total Synthesis of the Sesquiterpene (+)-Zizaene

10.1021/jacs.2c10923 · ExternalCitation · doi-reference

A Data-Driven Workflow for Assigning and Predicting Generality in Asymmetric Catalysis

10.1021/jacs.3c03989 · ExternalCitation · doi-reference

Silver(I)/Dirhodium(II) Catalytic Platform for Asymmetric N–H Insertion Reaction of Heteroaromatics

10.1021/jacs.3c10596 · ExternalCitation · doi-reference

Ruthenium-Catalyzed Asymmetric Hydrohydroxyalkylation of Butadiene: The Role of the Formyl Hydrogen Bond in Stereochemical Control

10.1021/jacs.5b04844 · ExternalCitation · doi-reference

Anti-Markovnikov Hydroamination of Homoallylic Amines

10.1021/jacs.5b08500 · ExternalCitation · doi-reference

Stereoselective Generalizations over Diverse Sets of Chiral Acids Enabled by Buried Volume

10.1021/jacs.5c20342 · ExternalCitation · doi-reference

Goldilocks Catalysts: Computational Insights into the Role of the 3,3′ Substituents on the Selectivity of BINOL-Derived Phosphoric Acid Catalysts

10.1021/jacs.6b02825 · ExternalCitation · doi-reference

A Novel Example of Chiral Counteranion Induced Enantioselective Metal Catalysis: The Importance of Ion-Pairing in Copper-Catalyzed Olefin Aziridination and Cyclopropanation

10.1021/ol000303y · ExternalCitation · doi-reference

A Concise Total Synthesis of Pyrovellerolactone Using a Rhodium-Catalyzed [(3+2)+2] Carbocyclization Reaction

10.1021/ol400165x · ExternalCitation · doi-reference

Nickel-Catalyzed Intramolecular [3+2+2] Cycloadditions of Alkylidenecyclopropanes. A Straightforward Entry to Fused 6,7,5-Tricyclic Systems

10.1021/ol502288x · ExternalCitation · doi-reference

A Chiral Phosphoramidite beyond Monodentate Coordination: Secondary π-Interactions Turn a Dangling Aryl into a Two-, Four-, or Six-Electron Donor in d6 and d8 Complexes

10.1021/om800064r · ExternalCitation · doi-reference

Ion-Paired Chiral Ligands for Asymmetric Palladium Catalysis

10.1038/nchem.1311 · ExternalCitation · doi-reference

The Progression of Chiral Anions from Concepts to Applications in Asymmetric Catalysis

10.1038/nchem.1405 · ExternalCitation · doi-reference

Towards the Online Computer-Aided Design of Catalytic Pockets

10.1038/s41557-019-0319-5 · ExternalCitation · doi-reference

Enantioselective Transition-Metal Catalysis via an Anion-Binding Approach

10.1038/s41586-023-05804-3 · ExternalCitation · doi-reference

Recent Developments in Chiral Anion Mediated Asymmetric Chemistry

10.1039/b205251m · ExternalCitation · doi-reference

Chiral Anion-Mediated Asymmetric Ion Pairing Chemistry

10.1039/b912530b · ExternalCitation · doi-reference

Stereoselective Transition Metal-Catalysed Higher-Order Carbocyclisation Reactions

10.1039/b913110h · ExternalCitation · doi-reference

Palladium-Catalyzed [3C+2C+2C] Cycloaddition of Enynylidenecyclopropanes: Efficient Construction of Fused 5–7–5 Tricyclic Systems

10.1039/b919258a · ExternalCitation · doi-reference

Atroposelective [2+2+2] Cycloadditions Catalyzed by a Rhodium(I)–Chiral Phosphate System

10.1039/c3cc43188f · ExternalCitation · doi-reference

Chiral Phosphoric Acid Catalysis: From Numbers to Insights

10.1039/c6cs00475j · ExternalCitation · doi-reference

Recent Advances in the Chemical Transformations of Functionalized Alkylidenecyclopropanes (FACPs)

10.1039/c7cc02596c · ExternalCitation · doi-reference

Cycloaddition of Cyclopropanes for the Elaboration of Medium-Sized Carbocycles

10.1039/d1ob00838b · ExternalCitation · doi-reference

Identifying the True Origins of Selectivity in Chiral Phosphoric Acid Catalyzed N-Acyl-azetidine Desymmetrizations

10.1039/d1sc04969k · ExternalCitation · doi-reference

Stereoselective Transition Metal-Catalyzed [(2+2)+1] and [(2+2)+2] Carbocyclization Reactions Using 1,6-Enynes with 1,1-Disubstituted Olefins: Construction of Quaternary Centers

10.1039/d4sc02645d · ExternalCitation · doi-reference

Trimethylenemethane Metal Complexes. Part 1. Synthesis of Ruthenium, Osmium, Rhodium, and Iridium Complexes

10.1039/dt9860001411 · ExternalCitation · doi-reference

Trimethylenemethane Complexes of Ruthenium, Osmium and Rhodium via the Compound CH2=C(CH2SnMe3)2

10.1039/dt9930002471 · ExternalCitation · doi-reference

Recent Developments in Polyene Cyclizations and Their Applications in Natural Product Synthesis

10.1055/s-0037-1610382 · ExternalCitation · doi-reference

Recent Advances in Transition-Metal-Catalyzed (4+3)-Cycloadditions

10.1055/s-0039-1690875 · ExternalCitation · doi-reference

Rhodium-Catalysed Chemo- and Regio-selective [3+2+2] Cycloadditions of bis(methylenecyclopropanes) and Alkynes: Synthesis of Spirocyclic 5–7 Condensed Cycloheptenes

10.1080/00397911.2020.1720738 · ExternalCitation · doi-reference

A Powerful Chiral Counterion Strategy for Asymmetric Transition Metal Catalysis

10.1126/science.1145229 · ExternalCitation · doi-reference

A Counterion Strategy

10.1126/science.1146922 · ExternalCitation · doi-reference

Enantioselective C-H Crotylation of Primary Alcohols via Hydrohydroxyalkylation of Butadiene

10.1126/science.1219274 · ExternalCitation · doi-reference

Chiral Monophosphines as Ligands for Asymmetric Organometallic Catalysis

10.1248/cpb.48.315 · ExternalCitation · doi-reference

Development of Transition-Metal-Catalyzed Cycloaddition Reactions Leading to Polycarbocyclic Systems

10.1351/pac-con-10-10-23 · ExternalCitation · doi-reference

Alkenylidenecyclopropanes (ACPs) as Three-Carbon Synthons in Transition-Metal-Catalyzed Cycloadditions

10.3390/catal16040287 · ExternalCitation · doi-reference