Research graph
References from Electron-Reservoir Multiple Bond in RhC– for Dinitrogen Cleavage. Local targets link to admitted publications; unresolved targets remain external evidence.
The Atom and the Molecule
10.1021/ja02261a002 · 1916 · External reference
Mononuclear and Polynuclear Chemistry of Rhenium (III): Its Pronounced Homophilicity
10.1126/science.145.3638.1305 · 1964 · External reference
Metal-Metal Bonding in [Re2X8]2– Ions and Other Metal Atom Clusters
10.1021/ic50025a016 · 1965 · External reference
Building a Quintuple Bond
10.1126/science.1120281 · 2005 · External reference
Quantum Chemical Calculations show that the Uranium Molecule U2 has a Quintuple Bond
10.1038/nature03330 · 2005 · External reference
The Six-Bond Bound
10.1038/446276a · 2007 · External reference
Ultrashort Metal–Metal Distances and Extreme Bond Orders
10.1038/nchem.359 · 2009 · External reference
Relativistic Quantum Chemical Calculations show that the Uranium Molecule U2 has a Quadruple Bond
10.1038/s41557-018-0158-9 · 2019 · External reference
Synthesis of a Stable Compound with Fivefold Bonding Between Two Chromium(I) Centers
10.1126/science.1116789 · 2005 · External reference
Reaching the Maximum Multiplicity of the Covalent Chemical Bond
10.1002/anie.200603600 · 2007 · External reference
Heterodinuclear Transition-Metal Complexes with Multiple Metal-Metal Bonds
10.1002/1521-3773(20021104)41:21<3948::aid-anie3948>3.0.co;2-k · 2002 · External reference
Heterobimetallic Complexes Containing Ca–Fe or Yb–Fe Bonds: Synthesis and Molecular and Electronic Structures of [M{CpFe(CO)2}2(THF)3]2 (M = Ca or Yb)
10.1021/ja207487j · 2011 · External reference
Configuring Bonds between First-Row Transition Metals
10.1021/acs.accounts.5b00336 · 2015 · External reference
Heterobimetallic Complexes Comprised of Nb and Fe: Isolation of a Coordinatively Unsaturated NbIII/Fe0 Bimetallic Complex Featuring a Nb≡Fe Triple Bond
10.1021/jacs.7b04151 · 2017 · External reference
Triple Bonds Between Iron and Heavier Group 15 Elements in AFe(CO)3– (A=As, Sb, Bi) Complexes
10.1002/anie.201709875 · 2018 · External reference
A Very Short Uranium(IV)–Rhodium(I) Bond with Net Double-Dative Bonding Character
10.1002/anie.201803493 · 2018 · External reference
Alkali Metal Covalent Bonding in Nickel Carbonyl Complexes ENi(CO)3–
10.1002/anie.201813022 · 2019 · External reference
Multiple Bonding Between Group 3 Metals and Fe(CO)3–
10.1002/anie.201914536 · 2020 · External reference
BeM(CO)3– (M = Co, Rh, Ir) and BeM(CO)3 (M = Ni, Pd, Pt): Triply Bonded Terminal Beryllium in Zero Oxidation State
10.1063/5.0181343 · 2024 · External reference
Formation and Characterization of BeFe(CO)4– Anion with Beryllium–Iron Bonding
10.1002/anie.202015760 · 2021 · External reference
Quadruple Bonding in C2 and Analogous Eight-Valence Electron Species
10.1038/nchem.1263 · 2012 · External reference
Insights into the Perplexing Nature of the Bonding in C2 from Generalized Valence Bond Calculations
10.1021/ct400867h · 2014 · External reference
One Molecule, Two Atoms, Three Views, Four Bonds?
10.1002/anie.201208206 · 2013 · External reference
The Quadruple Bonding in C2 Reproduces the Properties of the Molecule
10.1002/chem.201600011 · 2016 · External reference
The Dicarbon Bonding Puzzle viewed with Photoelectron Imaging
10.1038/s41467-019-13039-y · 2019 · External reference
The strength of the σ-, π- and δ-bonds in Re2Cl82–
10.1007/s00214-007-0294-6 · 2008 · External reference
Bonding Analysis of Metal–Metal Multiple Bonds in R3M–M′R3(M, M′ = Cr, Mo, W; R = Cl, NMe2)
10.1021/ic101227u · 2011 · External reference
Understanding the Uniqueness of 2p Elements in Periodic Tables
10.1002/chem.202003920 · 2020 · External reference
On the Maximum Bond Multiplicity of Carbon: Unusual C≣U Quadruple Bonding in Molecular CUO
10.1039/c2sc20329d · 2012 · External reference
Quadruple Bonding between Iron and Boron in the BFe(CO)3– Complex
10.1038/s41467-019-12767-5 · 2019 · External reference
Observation of Four-Fold Boron–Metal Bonds in RhB(BO–) and RhB
10.1021/acs.jpclett.9b03484 · 2020 · External reference
Spectroscopy and Bonding Analysis of ArnBO+ (n = 1–3) Cations That Possess Argon–Boron Multiple Bonds
10.1021/jacs.4c13459 · 2025 · External reference
The Unusual Quadruple Bonding of Nitrogen in ThN
10.1038/s41467-023-43208-z · 2023 · External reference
Genuine Quadruple Bonds between Two Main-Group Atoms. Chemical Bonding in AeF– (Ae = Be–Ba) and Isoelectronic EF (E = B–Tl) and the Particular Role of d Orbitals in Covalent Interactions of Heavier Alkaline-Earth Atoms
10.1039/d3sc00830d · 2023 · External reference
Unusual Quadruple Bonds Featuring Collective Interaction-Type σ Bonds between First Octal-Row Atoms in the Alkaline-Earth Compounds AeOLi2 (Ae = Be–Ba)
10.1039/d4sc01979b · 2024 · External reference
Analysis of the Unusual Chemical Bonds and Dipole Moments of AeF– (Ae=Be–Ba): A Lesson in Covalent Bonding
10.1002/chem.202304136 · 2024 · External reference
Quadruple Bonding between Carbon and Transition Metal in the Global Minimum Geometry of CM(BO)(CO)2– (M = Ru, Os)
10.1063/5.0291773 · 2025 · External reference
Quadruple Bonding in the Ground and Low-Lying Excited States of the Diatomic Molecules TcN, RuC, RhB, and PdBe
10.1021/acs.jpca.0c03208 · 2020 · External reference
Bond Dissociation Energies of FeB, CoB, NiB, RuB, RhB, OsB, IrB, and PtB
10.1063/1.5113511 · 2019 · External reference
Chemical Bonding and Electronic Structure of the Early Transition Metal Borides: ScB, TiB, VB, YB, ZrB, NbB, LaB, HfB, TaB, and WB
10.1021/acs.jpca.1c02886 · 2021 · External reference
Triple Bonding between Beryllium and Nitrogen in HNBeCO
10.1039/d2cc02969c · 2022 · External reference
s-Block Multiple Bonds: Isolation of a Beryllium Imido Complex
10.1002/anie.202016027 · 2021 · External reference
Metal-Centered Oxygen Atom Transfer Reactions
10.1021/cr00082a005 · 1987 · External reference
An IrVO4+ Cluster Catalytically Oxidizes Four CO Molecules: Importance of Ir–V Multiple Bonding
10.1021/acs.jpclett.1c01584 · 2021 · External reference
A Facile N≡N Bond Cleavage by the Trinuclear Metal Center in Vanadium Carbide Cluster Anions V3C4–
10.1021/jacs.0c02021 · 2020 · External reference
Dinitrogen Activation by Heteronuclear Metal Carbide Cluster Anions FeTaC2–: A 5d Early and 3d Late Transition Metal Strategy
10.1021/jacs.1c10018 · 2021 · External reference
Dinitrogen Activation and Cyanide Release by the Gas-Phase Cluster Anions InNbC2–: Synergistic Effects of the p-Block Indium and the d-Block Niobium
10.1021/jacs.5c06920 · 2025 · External reference
Observation of Competing Nitrogen Activation in Metal Tricarbon Anions MC3– (M = Os, Ir, Pt)
10.1039/d5sc04467g · 2025 · External reference
Spectroscopic Identification of the Dinitrogen Fixation and Activation by Metal Carbide Cluster Anions PtCn– (n = 4–6)
10.1021/acs.inorgchem.2c03150 · 2023 · External reference
Complete Cleavage of the N≡N Triple Bond by Ta2N+ via Degenerate Ligand Exchange at Ambient Temperature: A Perfect Catalytic Cycle
10.1073/pnas.1913664116 · 2019 · External reference
The Sequential Activation of H2 and N2 mediated by the Gas-Phase Sc3N+ Clusters: Formation of Amido Unit
10.1063/5.0029180 · 2021 · External reference
Dinitrogen Fixation and Reduction by Ta3N3H0,1– Cluster Anions at Room Temperature: Hydrogen-Assisted Enhancement of Reactivity
10.1021/jacs.9b03168 · 2019 · External reference
Photoelectron Spectroscopy and Formation Mechanism of Ta2N3–: Activation of N2 by Ta2N–
10.1063/5.0291038 · 2025 · External reference
Side-on-End-on Coordination of Dinitrogen on a Polynuclear Vanadium Nitride Cluster Anion
10.1002/chem.201904362 · 2019 · External reference
Room-Temperature Dinitrogen and Carbon Dioxide Activation to Form Nitrogen–Carbon Bonds by Quaternary Cluster Anions: Gold-Assisted Enhancement of Reactivity
10.1021/acs.jpclett.1c03774 · 2022 · External reference
Nitrogen Activation and Transformation on Monometallic Niobium Boron Oxide Cluster Anions at Room Temperature: A Dual-Site Mechanism
10.1021/acs.jpclett.1c01633 · 2021 · External reference
Dinitrogen Activation by Dihydrogen and Quaternary Cluster Anions AuNbBO–: Nb- and B-Mediated N2 Activation and Au-Assisted Nitrogen Transfer
10.1021/acs.jpclett.2c00945 · 2022 · External reference
Note: A Novel Dual-Channel Time-of-Flight Mass Spectrometer for Photoelectron Imaging Spectroscopy
10.1063/1.4811739 · 2013 · External reference
Reconstruction of Abel-Transformable Images: The Gaussian Basis-Set Expansion Abel Transform Method
10.1063/1.1482156 · 2002 · External reference
Unresolved reference
External reference
Generalized Gradient Approximation Made Simple
10.1103/physrevlett.77.3865 · 1996 · External reference
Self-Consistent Molecular Orbital Methods. XX. A Basis Set for Correlated Wave Functions
10.1063/1.438955 · 1980 · External reference
Contracted Gaussian Basis Sets for Molecular Calculations. I. Second Row atoms, Z=11–18
10.1063/1.438980 · 1980 · External reference
A Fifth-Order Perturbation Comparison of Electron Correlation Theories
10.1016/s0009-2614(89)87395-6 · 1989 · External reference
Toward Reliable Density Functional Methods without Adjustable Parameters: The PBE0Model
10.1063/1.478522 · 1999 · External reference
Developing Paradigms of Chemical Bonding: Adaptive Natural Density Partitioning
10.1039/b804083d · 2008 · External reference
Multiple Bonding in Rhodium Monoboride. Quasi-atomic Analyses of the Ground and Low-Lying Excited States
10.1021/acs.jpca.1c02860 · 2021 · External reference
Quadruple Bonds in MoC: Accurate Calculations and Precise Measurement of the Dissociation Energy of Low-Lying States of MoC
10.1063/5.0211422 · 2024 · External reference
A Fast Intrinsic Localization Procedure Applicable for Ab Initio and Semiempirical Linear Combination of Atomic Orbital Wave Functions
10.1063/1.456588 · 1989 · External reference
The Chemical Bonding and Electronic Structure of RhC, RhN, and RhO by Anion Photoelectron Spectroscopy
10.1063/1.477143 · 1998 · External reference
Heterodinuclear Transition-Metal Complexes with Multiple Metal-Metal Bonds
10.1002/1521-3773(20021104)41:21<3948::aid-anie3948>3.0.co;2-k · ExternalCitation · doi-reference
Reaching the Maximum Multiplicity of the Covalent Chemical Bond
10.1002/anie.200603600 · ExternalCitation · doi-reference
One Molecule, Two Atoms, Three Views, Four Bonds?
10.1002/anie.201208206 · ExternalCitation · doi-reference
Triple Bonds Between Iron and Heavier Group 15 Elements in AFe(CO)3– (A=As, Sb, Bi) Complexes
10.1002/anie.201709875 · ExternalCitation · doi-reference
A Very Short Uranium(IV)–Rhodium(I) Bond with Net Double-Dative Bonding Character
10.1002/anie.201803493 · ExternalCitation · doi-reference
Alkali Metal Covalent Bonding in Nickel Carbonyl Complexes ENi(CO)3–
10.1002/anie.201813022 · ExternalCitation · doi-reference
Multiple Bonding Between Group 3 Metals and Fe(CO)3–
10.1002/anie.201914536 · ExternalCitation · doi-reference
Formation and Characterization of BeFe(CO)4– Anion with Beryllium–Iron Bonding
10.1002/anie.202015760 · ExternalCitation · doi-reference
s-Block Multiple Bonds: Isolation of a Beryllium Imido Complex
10.1002/anie.202016027 · ExternalCitation · doi-reference
The Quadruple Bonding in C2 Reproduces the Properties of the Molecule
10.1002/chem.201600011 · ExternalCitation · doi-reference
Side-on-End-on Coordination of Dinitrogen on a Polynuclear Vanadium Nitride Cluster Anion
10.1002/chem.201904362 · ExternalCitation · doi-reference
Understanding the Uniqueness of 2p Elements in Periodic Tables
10.1002/chem.202003920 · ExternalCitation · doi-reference
Analysis of the Unusual Chemical Bonds and Dipole Moments of AeF– (Ae=Be–Ba): A Lesson in Covalent Bonding
10.1002/chem.202304136 · ExternalCitation · doi-reference
The strength of the σ-, π- and δ-bonds in Re2Cl82–
10.1007/s00214-007-0294-6 · ExternalCitation · doi-reference
A Fifth-Order Perturbation Comparison of Electron Correlation Theories
10.1016/s0009-2614(89)87395-6 · ExternalCitation · doi-reference
Configuring Bonds between First-Row Transition Metals
10.1021/acs.accounts.5b00336 · ExternalCitation · doi-reference
Spectroscopic Identification of the Dinitrogen Fixation and Activation by Metal Carbide Cluster Anions PtCn– (n = 4–6)
10.1021/acs.inorgchem.2c03150 · ExternalCitation · doi-reference
Quadruple Bonding in the Ground and Low-Lying Excited States of the Diatomic Molecules TcN, RuC, RhB, and PdBe
10.1021/acs.jpca.0c03208 · ExternalCitation · doi-reference
Multiple Bonding in Rhodium Monoboride. Quasi-atomic Analyses of the Ground and Low-Lying Excited States
10.1021/acs.jpca.1c02860 · ExternalCitation · doi-reference
Chemical Bonding and Electronic Structure of the Early Transition Metal Borides: ScB, TiB, VB, YB, ZrB, NbB, LaB, HfB, TaB, and WB
10.1021/acs.jpca.1c02886 · ExternalCitation · doi-reference
An IrVO4+ Cluster Catalytically Oxidizes Four CO Molecules: Importance of Ir–V Multiple Bonding
10.1021/acs.jpclett.1c01584 · ExternalCitation · doi-reference
Nitrogen Activation and Transformation on Monometallic Niobium Boron Oxide Cluster Anions at Room Temperature: A Dual-Site Mechanism
10.1021/acs.jpclett.1c01633 · ExternalCitation · doi-reference
Room-Temperature Dinitrogen and Carbon Dioxide Activation to Form Nitrogen–Carbon Bonds by Quaternary Cluster Anions: Gold-Assisted Enhancement of Reactivity
10.1021/acs.jpclett.1c03774 · ExternalCitation · doi-reference
Dinitrogen Activation by Dihydrogen and Quaternary Cluster Anions AuNbBO–: Nb- and B-Mediated N2 Activation and Au-Assisted Nitrogen Transfer
10.1021/acs.jpclett.2c00945 · ExternalCitation · doi-reference
Observation of Four-Fold Boron–Metal Bonds in RhB(BO–) and RhB
10.1021/acs.jpclett.9b03484 · ExternalCitation · doi-reference
Metal-Centered Oxygen Atom Transfer Reactions
10.1021/cr00082a005 · ExternalCitation · doi-reference
Insights into the Perplexing Nature of the Bonding in C2 from Generalized Valence Bond Calculations
10.1021/ct400867h · ExternalCitation · doi-reference
Bonding Analysis of Metal–Metal Multiple Bonds in R3M–M′R3(M, M′ = Cr, Mo, W; R = Cl, NMe2)
10.1021/ic101227u · ExternalCitation · doi-reference
Metal-Metal Bonding in [Re2X8]2– Ions and Other Metal Atom Clusters
10.1021/ic50025a016 · ExternalCitation · doi-reference
The Atom and the Molecule
10.1021/ja02261a002 · ExternalCitation · doi-reference
Heterobimetallic Complexes Containing Ca–Fe or Yb–Fe Bonds: Synthesis and Molecular and Electronic Structures of [M{CpFe(CO)2}2(THF)3]2 (M = Ca or Yb)
10.1021/ja207487j · ExternalCitation · doi-reference
A Facile N≡N Bond Cleavage by the Trinuclear Metal Center in Vanadium Carbide Cluster Anions V3C4–
10.1021/jacs.0c02021 · ExternalCitation · doi-reference
Dinitrogen Activation by Heteronuclear Metal Carbide Cluster Anions FeTaC2–: A 5d Early and 3d Late Transition Metal Strategy
10.1021/jacs.1c10018 · ExternalCitation · doi-reference
Spectroscopy and Bonding Analysis of ArnBO+ (n = 1–3) Cations That Possess Argon–Boron Multiple Bonds
10.1021/jacs.4c13459 · ExternalCitation · doi-reference
Dinitrogen Activation and Cyanide Release by the Gas-Phase Cluster Anions InNbC2–: Synergistic Effects of the p-Block Indium and the d-Block Niobium
10.1021/jacs.5c06920 · ExternalCitation · doi-reference
Heterobimetallic Complexes Comprised of Nb and Fe: Isolation of a Coordinatively Unsaturated NbIII/Fe0 Bimetallic Complex Featuring a Nb≡Fe Triple Bond
10.1021/jacs.7b04151 · ExternalCitation · doi-reference
Dinitrogen Fixation and Reduction by Ta3N3H0,1– Cluster Anions at Room Temperature: Hydrogen-Assisted Enhancement of Reactivity
10.1021/jacs.9b03168 · ExternalCitation · doi-reference
The Six-Bond Bound
10.1038/446276a · ExternalCitation · doi-reference
Quantum Chemical Calculations show that the Uranium Molecule U2 has a Quintuple Bond
10.1038/nature03330 · ExternalCitation · doi-reference
Quadruple Bonding in C2 and Analogous Eight-Valence Electron Species
10.1038/nchem.1263 · ExternalCitation · doi-reference
Ultrashort Metal–Metal Distances and Extreme Bond Orders
10.1038/nchem.359 · ExternalCitation · doi-reference
Quadruple Bonding between Iron and Boron in the BFe(CO)3– Complex
10.1038/s41467-019-12767-5 · ExternalCitation · doi-reference
The Dicarbon Bonding Puzzle viewed with Photoelectron Imaging
10.1038/s41467-019-13039-y · ExternalCitation · doi-reference
The Unusual Quadruple Bonding of Nitrogen in ThN
10.1038/s41467-023-43208-z · ExternalCitation · doi-reference
Relativistic Quantum Chemical Calculations show that the Uranium Molecule U2 has a Quadruple Bond
10.1038/s41557-018-0158-9 · ExternalCitation · doi-reference
Developing Paradigms of Chemical Bonding: Adaptive Natural Density Partitioning
10.1039/b804083d · ExternalCitation · doi-reference
On the Maximum Bond Multiplicity of Carbon: Unusual C≣U Quadruple Bonding in Molecular CUO
10.1039/c2sc20329d · ExternalCitation · doi-reference
Triple Bonding between Beryllium and Nitrogen in HNBeCO
10.1039/d2cc02969c · ExternalCitation · doi-reference
Genuine Quadruple Bonds between Two Main-Group Atoms. Chemical Bonding in AeF– (Ae = Be–Ba) and Isoelectronic EF (E = B–Tl) and the Particular Role of d Orbitals in Covalent Interactions of Heavier Alkaline-Earth Atoms
10.1039/d3sc00830d · ExternalCitation · doi-reference
Unusual Quadruple Bonds Featuring Collective Interaction-Type σ Bonds between First Octal-Row Atoms in the Alkaline-Earth Compounds AeOLi2 (Ae = Be–Ba)
10.1039/d4sc01979b · ExternalCitation · doi-reference
Observation of Competing Nitrogen Activation in Metal Tricarbon Anions MC3– (M = Os, Ir, Pt)
10.1039/d5sc04467g · ExternalCitation · doi-reference
Reconstruction of Abel-Transformable Images: The Gaussian Basis-Set Expansion Abel Transform Method
10.1063/1.1482156 · ExternalCitation · doi-reference
Self-Consistent Molecular Orbital Methods. XX. A Basis Set for Correlated Wave Functions
10.1063/1.438955 · ExternalCitation · doi-reference
Contracted Gaussian Basis Sets for Molecular Calculations. I. Second Row atoms, Z=11–18
10.1063/1.438980 · ExternalCitation · doi-reference
A Fast Intrinsic Localization Procedure Applicable for Ab Initio and Semiempirical Linear Combination of Atomic Orbital Wave Functions
10.1063/1.456588 · ExternalCitation · doi-reference
The Chemical Bonding and Electronic Structure of RhC, RhN, and RhO by Anion Photoelectron Spectroscopy
10.1063/1.477143 · ExternalCitation · doi-reference
Toward Reliable Density Functional Methods without Adjustable Parameters: The PBE0Model
10.1063/1.478522 · ExternalCitation · doi-reference
Note: A Novel Dual-Channel Time-of-Flight Mass Spectrometer for Photoelectron Imaging Spectroscopy
10.1063/1.4811739 · ExternalCitation · doi-reference
Bond Dissociation Energies of FeB, CoB, NiB, RuB, RhB, OsB, IrB, and PtB
10.1063/1.5113511 · ExternalCitation · doi-reference
The Sequential Activation of H2 and N2 mediated by the Gas-Phase Sc3N+ Clusters: Formation of Amido Unit
10.1063/5.0029180 · ExternalCitation · doi-reference
BeM(CO)3– (M = Co, Rh, Ir) and BeM(CO)3 (M = Ni, Pd, Pt): Triply Bonded Terminal Beryllium in Zero Oxidation State
10.1063/5.0181343 · ExternalCitation · doi-reference
Quadruple Bonds in MoC: Accurate Calculations and Precise Measurement of the Dissociation Energy of Low-Lying States of MoC
10.1063/5.0211422 · ExternalCitation · doi-reference
Photoelectron Spectroscopy and Formation Mechanism of Ta2N3–: Activation of N2 by Ta2N–
10.1063/5.0291038 · ExternalCitation · doi-reference
Quadruple Bonding between Carbon and Transition Metal in the Global Minimum Geometry of CM(BO)(CO)2– (M = Ru, Os)
10.1063/5.0291773 · ExternalCitation · doi-reference
Complete Cleavage of the N≡N Triple Bond by Ta2N+ via Degenerate Ligand Exchange at Ambient Temperature: A Perfect Catalytic Cycle
10.1073/pnas.1913664116 · ExternalCitation · doi-reference
Generalized Gradient Approximation Made Simple
10.1103/physrevlett.77.3865 · ExternalCitation · doi-reference
Synthesis of a Stable Compound with Fivefold Bonding Between Two Chromium(I) Centers
10.1126/science.1116789 · ExternalCitation · doi-reference
Building a Quintuple Bond
10.1126/science.1120281 · ExternalCitation · doi-reference
Mononuclear and Polynuclear Chemistry of Rhenium (III): Its Pronounced Homophilicity
10.1126/science.145.3638.1305 · ExternalCitation · doi-reference
