2D MoS ₂ /Au Interfaces For Enhanced Opto–Electronic Response With Sub‐Bandgap Photons

ABSTRACT Monolayer is a direct bandgap semiconductor with potential applications in optoelectronics and photonics. also has a large optical nonlinearity. However, the atomic thickness of the monolayer limits the strength of the measured functional signals, such as the photocurrent or photoluminescence, in optoelectronic devices. Here, we show that photocurrent in monolayer can be induced by sub‐bandgap photons by depositing Au nanoparticles on it. In this system, the nonlinear light–matter interaction in Au nanoparticles enhanced by the localized surface plasmons results in the generation of supercontinuum, which is reabsorbed by due to efficient resonant energy transfer. Au nanoparticle assisted photocurrent is more than an order of magnitude larger than two‐photon photocurrent in monolayer . Optimization of the shape, size and composition of the nanoparticle has the potential to enhance the photocurrent significantly with the prospect of applications in the detection of NIR photons, and related technologies including optical telecommunication.