Divergent construction of Ni and Fe–Al–H assemblies

Jordan R. Gipper; Kritika Gour; Nattamai Bhuvanesh; Manar M. Shoshani

doi:10.1039/d6cc05661j

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Divergent construction of Ni and Fe–Al–H assemblies

Jordan R. Gipper, Kritika Gour, Nattamai Bhuvanesh, Manar M. Shoshani

Chemical Communications2026doi:10.1039/d6cc05661j

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Abstract

Reaction of an Al-dihydride metalloligand with Ni( ii ) and Fe( ii ) halides affords heterotrimetallic hydrides featuring electron-rich transition-metal centers, with NiCl 2 undergoing reductive assembly and FeCl 2 hydride/halide metathesis.

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Jordan R. Gipper#1 Kritika Gour#2 Nattamai Bhuvanesh#3 Manar M. Shoshani#4

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Divergent construction of Ni and Fe–Al–H assemblies

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