Engineering local electrostatic contrast for synergistic CO 2 /N 2 separation in mixed-metal formate frameworks

Younghu Son; Bonsun Eo; Minjeong Park; Purna Chandra Rao; Kyungmin Choi; Sung Hwa Jhung; Minyoung Yoon

doi:10.1039/d6cc05828k

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Engineering local electrostatic contrast for synergistic CO 2 /N 2 separation in mixed-metal formate frameworks

Younghu Son, Bonsun Eo, Minjeong Park, Purna Chandra Rao, Kyungmin Choi, Sung Hwa Jhung, Minyoung Yoon

Chemical Communications2026doi:10.1039/d6cc05828k

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Abstract

Mixed-metal Mg x Mn 1− x (HCO 2 ) 2 shows a nonlinear CO 2 /N 2 selectivity maximum of 65.8 at Mg 0.75 Mn 0.25 , over twice either end member-linked to local electrostatic contrast.

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Younghu Son#1 Bonsun Eo#2 Minjeong Park#3 Purna Chandra Rao#4 Kyungmin Choi#5 Sung Hwa Jhung#6 Minyoung Yoon#7

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10.1039/c8cs00829a

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10.1039/c8cs00337h · 2019

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10.1002/anie.201000431 · 2010

Engineering local electrostatic contrast for synergistic CO 2 /N 2 separation in mixed-metal formate frameworks

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