Abstract
We report a pentacoordinated As(v) dication, [Ph(ppy)
2
As]
2+
, balancing stability and reactivity. Oxidation strengthens As–N chelation, forming a trigonal-bipyramidal geometry with Lewis acidity and base-triggered reactivity.
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Privacy-aware community infrastructureTaiki Adachi, Tomoki Yasui, Chihiro Okochi, Kenji Kanaori, Showa Kitajima, Hitoshi Kasai, Kouki Oka, Takahiro Iwamoto, Kensuke Naka, Hiroaki Imoto
Abstract
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10.1016/j.ccr.2011.01.028
10.1016/j.ccr.2011.01.028 · 2011
10.1002/anie.201307658
10.1002/anie.201307658 · 2014
10.1016/j.ccr.2016.05.010
10.1016/j.ccr.2016.05.010 · 2016
10.1002/anie.201310613
10.1002/anie.201310613 · 2014
10.1002/chem.201406469
10.1002/chem.201406469 · 2015
10.1002/chem.202004659
10.1002/chem.202004659 · 2021
10.1139/cjc-2024-0193
10.1139/cjc-2024-0193 · 2025
10.1002/chem.201405196
10.1002/chem.201405196 · 2014
10.1038/s41557-022-00913-4
10.1038/s41557-022-00913-4 · 2022
10.1002/anie.201902039
10.1002/anie.201902039 · 2019
10.1002/ejic.202400819
10.1002/ejic.202400819 · 2025
10.1246/cl.150657
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No ROR-resolved institution is linked to this work yet.
Provenance
crossref
Confidence 100%
pubmed
Confidence 98%
unpaywall
Confidence 95%
datacite
Confidence 0%
10.1246/cl.150657 · 2015
10.1021/jo01355a008
10.1021/jo01355a008 · 1957
10.1039/dt9840001349
10.1039/dt9840001349 · 1984
Unresolved referenced work
1994
10.1021/cr00088a005
10.1021/cr00088a005 · 1988
Unresolved referenced work
2005
10.1016/j.ccr.2005.03.031
10.1016/j.ccr.2005.03.031 · 2005
10.1021/ja00807a011
10.1021/ja00807a011 · 1973
10.1002/chem.201802698
10.1002/chem.201802698 · 2018
10.1002/cphc.202000244
10.1002/cphc.202000244 · 2020
10.1002/anie.200800783
10.1002/anie.200800783 · 2008
10.1002/anie.202011696
10.1002/anie.202011696 · 2020
10.1021/ja061715q
10.1021/ja061715q · 2006
10.1107/s0108767395007367
10.1107/s0108767395007367 · 1995
10.1107/s0021889812001124
10.1107/s0021889812001124 · 2012
10.1107/s2053273314026370
10.1107/s2053273314026370 · 2015
10.1107/s0021889808042726
10.1107/s0021889808042726 · 2009
10.1107/s2053229614024218
10.1107/s2053229614024218 · 2015
10.1002/jcc.25873
10.1002/jcc.25873 · 2019
10.1002/jcc.22885
10.1002/jcc.22885 · 2012
Unresolved referenced work
2002
10.5517/ccdc.csd.cc2rr76z
10.5517/ccdc.csd.cc2rr76z · 2026
10.5517/ccdc.csd.cc2rr770
10.5517/ccdc.csd.cc2rr770 · 2026
10.5517/ccdc.csd.cc2rr781
10.5517/ccdc.csd.cc2rr781 · 2026
10.5517/ccdc.csd.cc2rr792
10.5517/ccdc.csd.cc2rr792 · 2026
10.5517/ccdc.csd.cc2rzxc1
10.5517/ccdc.csd.cc2rzxc1 · 2026
No additional external references are available.