Bridging preferences in heteroleptic beryllium phenyl halide complexes

Magnus R. Buchner; Deniz F. Bekiş; Sergei I. Ivlev

doi:10.1039/d6dt02291j

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Bridging preferences in heteroleptic beryllium phenyl halide complexes

Magnus R. Buchner, Deniz F. Bekiş, Sergei I. Ivlev

Dalton Transactions2026doi:10.1039/d6dt02291j

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Abstract

The dinuclear complex [(PMe 3 )Be 2 Ph 3 I] bridges through two phenyl groups while the iodide remains terminal. Across the halide series, carbon and halide bridging are energetically closely balanced in Grignard-analogous beryllium chemistry.

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Magnus R. Buchner#1 Deniz F. Bekiş#2 Sergei I. Ivlev#3

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Bridging preferences in heteroleptic beryllium phenyl halide complexes

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