Abstract
Bismuth vanadate (BiVO4) has garnered significant interest as a promising photoelectrochemical (PEC) material for water splitting. However, its poor electron mobility, sluggish surface water oxidation kinetics, and high overpotential limit its PEC water splitting efficiency, making it significantly lower than its theoretical maximum. To address these challenges, a composite bifunctional molybdenum layer photoanode Nickel-Iron Oxyhydroxide/Molybdenum Oxide/Molydenum doped Bismuth Vanadate (NiFe/MoOx/Mo:BiVO4) was designed, incorporating Mo doped and a MoOx hole transfer layer (HTL) at the oxygen evolution catalyst (OEC)/BiVO4 interface, for highly efficient PEC water splitting. The NiFe/MoOx/Mo:BiVO4 photoanode exhibited a photocurrent density of 5.29 mA cm-2 at 1.23 VRHE, approximately three times higher than that of pristine BiVO4. It also achieves an applied bias photon to current conversion efficiency (ABPE) value of 1.83%, representing a significant improvement over the 0.37% observed for pristine BiVO4. Electrochemical analyses and density functional theory (DFT) calculations indicate that Mo doping improves bulk charge transfer, while the incorporation of a MoOx HTL facilitates interfacial charge separation. Additionally, the synergistic effects of Mo doping and the MoOx HTL contribute to accelerating the kinetics of water splitting. These findings provide valuable insights for the rational design and development of integrated photoanodes for efficient solar energy conversion.